CHROMATOGRAPHIC INVESTIGATION OF RUTHENIUM NITROSYL COMPLEX: NO INTERCONVERSION AND REACTIONS WITH BIOLOGICAL REDUCTANTS

CHROMATOGRAPHIC INVESTIGATION OF RUTHENIUM NITROSYL COMPLEX: NO INTERCONVERSION AND REACTIONS WITH BIOLOGICAL REDUCTANTS

One experimental strategy to prepare a nitrosyl metal complex is based on the acid-base conversion of NO2- into NO+. Here, we employed UV-vis absorption and FTIR spectroscopies to investigate the reaction of cis-[Ru(NO2)(bpy)2(imN)]PF6 with H3O+, which produced cis-[Ru(NO)(bpy)2(imN)](PF6)3 complex....

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Bibliographic Details
Main Authors:	Francisco O. N. da Silva, Dayana P. S. Penha, Ana E. V. de Alencar, Daniel de L. Pontes, Ana C. F. de B. Pontes, Eduardo H. S. Sousa, Luiz G. F. Lopes
Format:	Article
Language:	English
Published:	Sociedade Brasileira de Química
Series:	Química Nova
Subjects:	nitrite/nitrosyl interconversion ruthenium cysteine and HPLC
Online Access:	http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000400400&lng=en&tlng=en

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