Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate

Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate

In the title compound, C20H18Cl2N4O8, the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, intermolecular C—H...N hydrogen bonds link neighbourin...

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Main Authors: Hoong-Kun Fun, Jia Hao Goh, Sankappa Rai, Arun M. Isloor, Prakash Shetty
Format: Article
Language:English
Published: International Union of Crystallography 2010-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810024785
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spelling doaj-29cbbbe0012b430b93e41a800c915e8f2020-11-24T21:29:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-07-01667o1869o187010.1107/S1600536810024785Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoateHoong-Kun FunJia Hao GohSankappa RaiArun M. IsloorPrakash ShettyIn the title compound, C20H18Cl2N4O8, the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, intermolecular C—H...N hydrogen bonds link neighbouring molecules into a ribbon-like structure along the b axis. The ribbons are interconnected into a two-dimensional network parallel to the bc plane by short intermolecular Cl...Cl [3.4427 (6) Å] and Cl...O [3.1420 (9) and 3.1750 (11) Å] interactions. The crystal structure is further stabilized by intermolecular π–π interactions [centroid–centroid distance 3.4552 (8) Å] involving the pyrimidine rings. http://scripts.iucr.org/cgi-bin/paper?S1600536810024785
collection DOAJ
language English
format Article
sources DOAJ
author Hoong-Kun Fun
Jia Hao Goh
Sankappa Rai
Arun M. Isloor
Prakash Shetty
spellingShingle Hoong-Kun Fun
Jia Hao Goh
Sankappa Rai
Arun M. Isloor
Prakash Shetty
Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate
Acta Crystallographica Section E
author_facet Hoong-Kun Fun
Jia Hao Goh
Sankappa Rai
Arun M. Isloor
Prakash Shetty
author_sort Hoong-Kun Fun
title Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate
title_short Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate
title_full Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate
title_fullStr Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate
title_full_unstemmed Methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate
title_sort methyl 2,6-bis[(5-chloro-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-07-01
description In the title compound, C20H18Cl2N4O8, the two pyrimidine rings are inclined at dihedral angles of 66.68 (5) and 71.91 (6)° with respect to the central benzene ring. In the crystal structure, intermolecular C—H...N hydrogen bonds link neighbouring molecules into a ribbon-like structure along the b axis. The ribbons are interconnected into a two-dimensional network parallel to the bc plane by short intermolecular Cl...Cl [3.4427 (6) Å] and Cl...O [3.1420 (9) and 3.1750 (11) Å] interactions. The crystal structure is further stabilized by intermolecular π–π interactions [centroid–centroid distance 3.4552 (8) Å] involving the pyrimidine rings.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810024785
work_keys_str_mv AT hoongkunfun methyl26bis5chloro46dimethoxypyrimidin2yloxybenzoate
AT jiahaogoh methyl26bis5chloro46dimethoxypyrimidin2yloxybenzoate
AT sankapparai methyl26bis5chloro46dimethoxypyrimidin2yloxybenzoate
AT arunmisloor methyl26bis5chloro46dimethoxypyrimidin2yloxybenzoate
AT prakashshetty methyl26bis5chloro46dimethoxypyrimidin2yloxybenzoate
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