catena-Poly[[[dibromidomanganese(II)]-μ-2,2′-bipyrimidine-κ4N1,N1′:N3,N3′]dihydrate]
The asymmetric unit of the title compound, {[MnBr2(C8H6N4)]·2H2O}n, contains one half of a repeat unit of the neutral linear coordination polymer and a solvent water molecule, with the MnII ion on a crystallographic twofold axis. In the polymer, inversion-related MnII ions are bridged b...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811049919 |
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doaj-297083a2d469453ca5d2d938af3f5e232020-11-24T21:45:47ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712m1848m184810.1107/S1600536811049919catena-Poly[[[dibromidomanganese(II)]-μ-2,2′-bipyrimidine-κ4N1,N1′:N3,N3′]dihydrate]Kwang HaThe asymmetric unit of the title compound, {[MnBr2(C8H6N4)]·2H2O}n, contains one half of a repeat unit of the neutral linear coordination polymer and a solvent water molecule, with the MnII ion on a crystallographic twofold axis. In the polymer, inversion-related MnII ions are bridged by the bis-chelating 2,2′-bipyrimidine (bpym) ligands, thereby forming a chain structure along the c-axis direction, and are six-coordinated in a distorted cis-N4Br2 octahedral environment by four N atoms of twofold-related bpym ligands and twofold-related bromide anions. In the crystal, the complex polymers and solvent water molecules are linked by intermolecular O—H...Br and C—H...O hydrogen bonds, forming a two-dimensional layered structure extending parallel to the ac plane.http://scripts.iucr.org/cgi-bin/paper?S1600536811049919 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Kwang Ha |
| spellingShingle |
Kwang Ha catena-Poly[[[dibromidomanganese(II)]-μ-2,2′-bipyrimidine-κ4N1,N1′:N3,N3′]dihydrate] Acta Crystallographica Section E |
| author_facet |
Kwang Ha |
| author_sort |
Kwang Ha |
| title |
catena-Poly[[[dibromidomanganese(II)]-μ-2,2′-bipyrimidine-κ4N1,N1′:N3,N3′]dihydrate] |
| title_short |
catena-Poly[[[dibromidomanganese(II)]-μ-2,2′-bipyrimidine-κ4N1,N1′:N3,N3′]dihydrate] |
| title_full |
catena-Poly[[[dibromidomanganese(II)]-μ-2,2′-bipyrimidine-κ4N1,N1′:N3,N3′]dihydrate] |
| title_fullStr |
catena-Poly[[[dibromidomanganese(II)]-μ-2,2′-bipyrimidine-κ4N1,N1′:N3,N3′]dihydrate] |
| title_full_unstemmed |
catena-Poly[[[dibromidomanganese(II)]-μ-2,2′-bipyrimidine-κ4N1,N1′:N3,N3′]dihydrate] |
| title_sort |
catena-poly[[[dibromidomanganese(ii)]-μ-2,2′-bipyrimidine-κ4n1,n1′:n3,n3′]dihydrate] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2011-12-01 |
| description |
The asymmetric unit of the title compound, {[MnBr2(C8H6N4)]·2H2O}n, contains one half of a repeat unit of the neutral linear coordination polymer and a solvent water molecule, with the MnII ion on a crystallographic twofold axis. In the polymer, inversion-related MnII ions are bridged by the bis-chelating 2,2′-bipyrimidine (bpym) ligands, thereby forming a chain structure along the c-axis direction, and are six-coordinated in a distorted cis-N4Br2 octahedral environment by four N atoms of twofold-related bpym ligands and twofold-related bromide anions. In the crystal, the complex polymers and solvent water molecules are linked by intermolecular O—H...Br and C—H...O hydrogen bonds, forming a two-dimensional layered structure extending parallel to the ac plane. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811049919 |
| work_keys_str_mv |
AT kwangha catenapolydibromidomanganeseiiamp95622amp8242bipyrimidineamp9544n1n1amp8242n3n3amp8242dihydrate |
| _version_ |
1725904242645925888 |