The Influence of Synthesis Parameters on Particle Size and Photoluminescence Characteristics of Ligand Capped Tb3+:LaF3

Organic ligand surface-treated Tb3+:LaF3 was synthesized in water and methanol for subsequent incorporation into polymethyl methacrylate (PMMA) via solution-precipitation chemistry in order to produce optically active polymer nanocomposites. Nanoparticle agglomerate diameters ranged from 388 ± 188 n...

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Bibliographic Details
Main Authors: Phil Brown, Kathryn Stevens, John Ballato, Kyle Gipson, Derek Stadther, Courtney Kucera
Format: Article
Language:English
Published: MDPI AG 2011-11-01
Series:Polymers
Subjects:
Online Access:http://www.mdpi.com/2073-4360/3/4/2039/
Description
Summary:Organic ligand surface-treated Tb3+:LaF3 was synthesized in water and methanol for subsequent incorporation into polymethyl methacrylate (PMMA) via solution-precipitation chemistry in order to produce optically active polymer nanocomposites. Nanoparticle agglomerate diameters ranged from 388 ± 188 nm when synthesized in water and 37 ± 2 nm when synthesized in methanol. Suspension stability is paramount for producing optically transparent materials. Methanol nanoparticle synthesized at a pH of 3 exhibited the smallest agglomerate size. Optical spectroscopy, dynamic light scattering, transmission electron microscopy, scanning transmission electron microscopy, and zeta potential analysis were used to characterize the particles synthesized.
ISSN:2073-4360