Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate

Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate

In the title complex, [Cu(C5H5N2O2)(C14H18N3O)(H2O)]·1.33H2O, the CuII ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ide li...

Full description

Bibliographic Details
Main Authors: Ji-Chang Zhuang, Fei-Long Hu, Zhong-Jing Huang, Yue Zhuang, Feng Zhang
Format: Article
Language:English
Published: International Union of Crystallography 2010-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809053768
id doaj-28fcc284082d46e5aad15fd127a917fe
record_format Article
spelling doaj-28fcc284082d46e5aad15fd127a917fe2020-11-25T00:59:44ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-01-01661m79m7910.1107/S1600536809053768Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrateJi-Chang ZhuangFei-Long HuZhong-Jing HuangYue ZhuangFeng ZhangIn the title complex, [Cu(C5H5N2O2)(C14H18N3O)(H2O)]·1.33H2O, the CuII ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ide ligand and by one O atom and one N atom from a 5-methyl-1H-pyrazole-3-carboxylate ligand. The apical position is occupied by a water molecule. In the crystal structure, O—H...O, O—H...N and N—H...O hydrogen bonds lead to a three-dimensional supramolecular network. http://scripts.iucr.org/cgi-bin/paper?S1600536809053768
collection DOAJ
language English
format Article
sources DOAJ
author Ji-Chang Zhuang
Fei-Long Hu
Zhong-Jing Huang
Yue Zhuang
Feng Zhang
spellingShingle Ji-Chang Zhuang
Fei-Long Hu
Zhong-Jing Huang
Yue Zhuang
Feng Zhang
Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate
Acta Crystallographica Section E
author_facet Ji-Chang Zhuang
Fei-Long Hu
Zhong-Jing Huang
Yue Zhuang
Feng Zhang
author_sort Ji-Chang Zhuang
title Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate
title_short Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate
title_full Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate
title_fullStr Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate
title_full_unstemmed Aqua[2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κN1](5-methyl-1H-pyrazole-3-carboxylato-κ2N2,O)copper(II) 1.33-hydrate
title_sort aqua[2-(5-ethyl-2-pyridyl-κn)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ido-κn1](5-methyl-1h-pyrazole-3-carboxylato-κ2n2,o)copper(ii) 1.33-hydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-01-01
description In the title complex, [Cu(C5H5N2O2)(C14H18N3O)(H2O)]·1.33H2O, the CuII ion is coordinated in a slightly distorted square-pyramidal environment. The basal plane is formed by two N atoms from a 2-(5-ethyl-2-pyridyl-κN)-4-isopropyl-4-methyl-5-oxo-4,5-dihydroxyimidazol-1-ide ligand and by one O atom and one N atom from a 5-methyl-1H-pyrazole-3-carboxylate ligand. The apical position is occupied by a water molecule. In the crystal structure, O—H...O, O—H...N and N—H...O hydrogen bonds lead to a three-dimensional supramolecular network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809053768
work_keys_str_mv AT jichangzhuang aqua25ethyl2pyridylamp954n4isopropyl4methyl5oxo45dihydroxyimidazol1idoamp954n15methyl1hpyrazole3carboxylatoamp9542n2ocopperii133hydrate
AT feilonghu aqua25ethyl2pyridylamp954n4isopropyl4methyl5oxo45dihydroxyimidazol1idoamp954n15methyl1hpyrazole3carboxylatoamp9542n2ocopperii133hydrate
AT zhongjinghuang aqua25ethyl2pyridylamp954n4isopropyl4methyl5oxo45dihydroxyimidazol1idoamp954n15methyl1hpyrazole3carboxylatoamp9542n2ocopperii133hydrate
AT yuezhuang aqua25ethyl2pyridylamp954n4isopropyl4methyl5oxo45dihydroxyimidazol1idoamp954n15methyl1hpyrazole3carboxylatoamp9542n2ocopperii133hydrate
AT fengzhang aqua25ethyl2pyridylamp954n4isopropyl4methyl5oxo45dihydroxyimidazol1idoamp954n15methyl1hpyrazole3carboxylatoamp9542n2ocopperii133hydrate
_version_ 1725216485212684288

Similar Items