Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one
In the title compound, C13H10ClNOS2, the dihedral angle between the rhodanine (r.m.s. deviation = 0.008 Å) and 4-chlorobenzylidene rings is 1.79 (11)°. The allyl group attached to the N atom, which lies almost perpendicular to the rhodanine ring, is disordered over two orientations in a 0.519 (13):0...
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International Union of Crystallography
2015-12-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015022689 |
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doaj-28bf525f534741b493a8ff61049ef0e12020-11-24T21:44:59ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-12-017112o1012o101210.1107/S2056989015022689hb7551Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-oneRahhal El Ajlaoui0El Mostapha Rakib1Souad Mojahidi2Mohamed Saadi3Lahcen El Ammari4Laboratoire de Chimie Organique et Analytique, Université Sultan Moulay Slimane, Faculté des Sciences et Techniques, Béni-Mellal, BP 523, MoroccoLaboratoire de Chimie Organique et Analytique, Université Sultan Moulay Slimane, Faculté des Sciences et Techniques, Béni-Mellal, BP 523, MoroccoLaboratoire de Chimie Organique et Analytique, Université Sultan Moulay Slimane, Faculté des Sciences et Techniques, Béni-Mellal, BP 523, MoroccoLaboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V de Rabat, Avenue Ibn Battouta, BP 1014, Rabat, MoroccoLaboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Université Mohammed V de Rabat, Avenue Ibn Battouta, BP 1014, Rabat, MoroccoIn the title compound, C13H10ClNOS2, the dihedral angle between the rhodanine (r.m.s. deviation = 0.008 Å) and 4-chlorobenzylidene rings is 1.79 (11)°. The allyl group attached to the N atom, which lies almost perpendicular to the rhodanine ring, is disordered over two orientations in a 0.519 (13):0.481 (13) ratio. A short intramolecular C—H...S interaction closes an S(6) ring. In the crystal, molecules are linked by π–π stacking interactions [centroid–centroid separation = 3.600 (15) Å], generating inversion dimers.http://scripts.iucr.org/cgi-bin/paper?S2056989015022689crystal structurerhodanine-based moleculespharmacological activitybiological activity1,3-thiazolidin-4-one |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Rahhal El Ajlaoui El Mostapha Rakib Souad Mojahidi Mohamed Saadi Lahcen El Ammari |
| spellingShingle |
Rahhal El Ajlaoui El Mostapha Rakib Souad Mojahidi Mohamed Saadi Lahcen El Ammari Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one Acta Crystallographica Section E: Crystallographic Communications crystal structure rhodanine-based molecules pharmacological activity biological activity 1,3-thiazolidin-4-one |
| author_facet |
Rahhal El Ajlaoui El Mostapha Rakib Souad Mojahidi Mohamed Saadi Lahcen El Ammari |
| author_sort |
Rahhal El Ajlaoui |
| title |
Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_short |
Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_full |
Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_fullStr |
Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_full_unstemmed |
Crystal structure of (Z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| title_sort |
crystal structure of (z)-3-allyl-5-(4-chlorobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E: Crystallographic Communications |
| issn |
2056-9890 |
| publishDate |
2015-12-01 |
| description |
In the title compound, C13H10ClNOS2, the dihedral angle between the rhodanine (r.m.s. deviation = 0.008 Å) and 4-chlorobenzylidene rings is 1.79 (11)°. The allyl group attached to the N atom, which lies almost perpendicular to the rhodanine ring, is disordered over two orientations in a 0.519 (13):0.481 (13) ratio. A short intramolecular C—H...S interaction closes an S(6) ring. In the crystal, molecules are linked by π–π stacking interactions [centroid–centroid separation = 3.600 (15) Å], generating inversion dimers. |
| topic |
crystal structure rhodanine-based molecules pharmacological activity biological activity 1,3-thiazolidin-4-one |
| url |
http://scripts.iucr.org/cgi-bin/paper?S2056989015022689 |
| work_keys_str_mv |
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| _version_ |
1725907380494925824 |