Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters

Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalyst...

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Main Authors:	Vicent Lloret, Miguel Ángel Rivero-Crespo, José Alejandro Vidal-Moya, Stefan Wild, Antonio Doménech-Carbó, Bettina S. J. Heller, Sunghwan Shin, Hans-Peter Steinrück, Florian Maier, Frank Hauke, Maria Varela, Andreas Hirsch, Antonio Leyva-Pérez, Gonzalo Abellán
Format:	Article
Language:	English
Published:	Nature Publishing Group 2019-01-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-018-08063-3

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spelling	doaj-28a596c09abf4115927d5c20f93f25ca2021-05-11T12:11:26ZengNature Publishing GroupNature Communications2041-17232019-01-0110111110.1038/s41467-018-08063-3Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with estersVicent Lloret0Miguel Ángel Rivero-Crespo1José Alejandro Vidal-Moya2Stefan Wild3Antonio Doménech-Carbó4Bettina S. J. Heller5Sunghwan Shin6Hans-Peter Steinrück7Florian Maier8Frank Hauke9Maria Varela10Andreas Hirsch11Antonio Leyva-Pérez12Gonzalo Abellán13Department of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Instituto de Tecnología Química, Universidad Politécnica de Valencia, Consejo Superior de Investigaciones CientíficasInstituto de Tecnología Química, Universidad Politécnica de Valencia, Consejo Superior de Investigaciones CientíficasDepartment of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Departamento de Química Analítica, Universidad de ValenciaChair of Physical Chemistry II, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Chair of Physical Chemistry II, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Chair of Physical Chemistry II, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Chair of Physical Chemistry II, Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Department of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Departamento de Física de Materiales, Universidad Complutense de Madrid, Instituto Pluridisciplinar, Instituto de Magnetismo AplicadoDepartment of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Instituto de Tecnología Química, Universidad Politécnica de Valencia, Consejo Superior de Investigaciones CientíficasDepartment of Chemistry and Pharmacy & Joint Institute of Advanced Materials and Processes (ZMP), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU)Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalysts for the alkylation of nucleophiles with esters.https://doi.org/10.1038/s41467-018-08063-3
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Vicent Lloret Miguel Ángel Rivero-Crespo José Alejandro Vidal-Moya Stefan Wild Antonio Doménech-Carbó Bettina S. J. Heller Sunghwan Shin Hans-Peter Steinrück Florian Maier Frank Hauke Maria Varela Andreas Hirsch Antonio Leyva-Pérez Gonzalo Abellán
spellingShingle	Vicent Lloret Miguel Ángel Rivero-Crespo José Alejandro Vidal-Moya Stefan Wild Antonio Doménech-Carbó Bettina S. J. Heller Sunghwan Shin Hans-Peter Steinrück Florian Maier Frank Hauke Maria Varela Andreas Hirsch Antonio Leyva-Pérez Gonzalo Abellán Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters Nature Communications
author_facet	Vicent Lloret Miguel Ángel Rivero-Crespo José Alejandro Vidal-Moya Stefan Wild Antonio Doménech-Carbó Bettina S. J. Heller Sunghwan Shin Hans-Peter Steinrück Florian Maier Frank Hauke Maria Varela Andreas Hirsch Antonio Leyva-Pérez Gonzalo Abellán
author_sort	Vicent Lloret
title	Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
title_short	Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
title_full	Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
title_fullStr	Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
title_full_unstemmed	Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters
title_sort	few layer 2d pnictogens catalyze the alkylation of soft nucleophiles with esters
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2019-01-01
description	Group 15 elements in zero oxidation state, also called pnictogens, are rarely used in catalysis due to the difficulties in preparation. Here, the authors report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, and their use as efficient catalysts for the alkylation of nucleophiles with esters.
url	https://doi.org/10.1038/s41467-018-08063-3
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Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters

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