Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps

Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps

Atom efficient processes such as the Diels–Alder reaction (DA) and the ring-rearrangement metathesis (RRM) have been used to design new polycycles. In this regard, ruthenium alkylidene catalysts are effective in realizing the RRM of bis-norbornene derivatives prepared by DA reaction and Grignard add...

Full description

Bibliographic Details
Main Authors: Sambasivarao Kotha, Ongolu Ravikumar
Format: Article
Language:English
Published: Beilstein-Institut 2015-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Diels–Alder reaction
Grignard addition
ring-rearrangement metathesis
polycycles
Online Access:https://doi.org/10.3762/bjoc.11.140
id doaj-289d1403886f4704ab9d7add91b419b0
record_format Article
spelling doaj-289d1403886f4704ab9d7add91b419b02021-02-02T01:03:04ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972015-07-011111259126410.3762/bjoc.11.1401860-5397-11-140Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key stepsSambasivarao Kotha0Ongolu Ravikumar1Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai-400 076, India, Fax: 022-25767152Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai-400 076, India, Fax: 022-25767152Atom efficient processes such as the Diels–Alder reaction (DA) and the ring-rearrangement metathesis (RRM) have been used to design new polycycles. In this regard, ruthenium alkylidene catalysts are effective in realizing the RRM of bis-norbornene derivatives prepared by DA reaction and Grignard addition. Here, fused polycycles are assembled which are difficult to produce by conventional synthetic routes.https://doi.org/10.3762/bjoc.11.140Diels–Alder reactionGrignard additionring-rearrangement metathesispolycycles
collection DOAJ
language English
format Article
sources DOAJ
author Sambasivarao Kotha
Ongolu Ravikumar
spellingShingle Sambasivarao Kotha
Ongolu Ravikumar
Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
Beilstein Journal of Organic Chemistry
Diels–Alder reaction
Grignard addition
ring-rearrangement metathesis
polycycles
author_facet Sambasivarao Kotha
Ongolu Ravikumar
author_sort Sambasivarao Kotha
title Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
title_short Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
title_full Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
title_fullStr Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
title_full_unstemmed Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
title_sort design and synthesis of fused polycycles via diels–alder reaction and ring-rearrangement metathesis as key steps
publisher Beilstein-Institut
series Beilstein Journal of Organic Chemistry
issn 1860-5397
publishDate 2015-07-01
description Atom efficient processes such as the Diels–Alder reaction (DA) and the ring-rearrangement metathesis (RRM) have been used to design new polycycles. In this regard, ruthenium alkylidene catalysts are effective in realizing the RRM of bis-norbornene derivatives prepared by DA reaction and Grignard addition. Here, fused polycycles are assembled which are difficult to produce by conventional synthetic routes.
topic Diels–Alder reaction
Grignard addition
ring-rearrangement metathesis
polycycles
url https://doi.org/10.3762/bjoc.11.140
work_keys_str_mv AT sambasivaraokotha designandsynthesisoffusedpolycyclesviadielsalderreactionandringrearrangementmetathesisaskeysteps
AT ongoluravikumar designandsynthesisoffusedpolycyclesviadielsalderreactionandringrearrangementmetathesisaskeysteps
_version_ 1724312446594711552

Similar Items