Correlation of Viscosity of Aqueous Solutions of Alkanolamine Mixtures Based on the Eyring's Theory and Wong-Sandler Mixing Rule

A viscosity model, based on Eyring’s absolute rate theory combined with a cubic PR equation of state and Wong-Sandler mixing rule, has been proposed in order to correlate viscosities of aqueous solutions of alkanolamine mixtures at atmospheric pressure and different temperatures. In the proposed met...

Full description

Bibliographic Details
Main Authors: Sara Ahmad Kelayeh, Cyrus Ghotbi, Vahid Taghikhani, Amir Jalili
Format: Article
Language:English
Published: Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 2013-06-01
Series:Iranian Journal of Chemistry & Chemical Engineering
Subjects:
Online Access:http://www.ijcce.ac.ir/article_5863_d4cf70090b6f82b504893d1e66d9f13a.pdf
id doaj-287ffedaf5d64c709bc48afcafcb35de
record_format Article
spelling doaj-287ffedaf5d64c709bc48afcafcb35de2020-11-25T03:28:23ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99862013-06-013229175863Correlation of Viscosity of Aqueous Solutions of Alkanolamine Mixtures Based on the Eyring's Theory and Wong-Sandler Mixing RuleSara Ahmad Kelayeh0Cyrus Ghotbi1Vahid Taghikhani2Amir Jalili3Department of Chemical & Petroleum Engineering, Sharif University of Technology, Tehran, I.R. IRANDepartment of Chemical & Petroleum Engineering, Sharif University of Technology, Tehran, I.R. IRANDepartment of Chemical & Petroleum Engineering, Sharif University of Technology, Tehran, I.R. IRANGas Science Department, Research Institute of Petroleum Industry (RIPI), Tehran, I.R. IRANA viscosity model, based on Eyring’s absolute rate theory combined with a cubic PR equation of state and Wong-Sandler mixing rule, has been proposed in order to correlate viscosities of aqueous solutions of alkanolamine mixtures at atmospheric pressure and different temperatures. In the proposed method, the energy and size parameters in studied Equation of State (EoS) have been obtained using the Wong – Sandler (WS) mixing rule combined with the NRTL and Wilson Gibbs equations. The NRTL and Wilson parameters for aqueous solutions of alkanolamine mixtures have been correlated using measured viscosity data at atmospheric pressure and different temperatures. The overall average deviation between the experimental and calculated viscosities of studied aqueous solutions of alkanolamine mixtures using Wilson model is 0.92%.http://www.ijcce.ac.ir/article_5863_d4cf70090b6f82b504893d1e66d9f13a.pdfws mixing ruleviscosity modelsequation of statenrtlwilson
collection DOAJ
language English
format Article
sources DOAJ
author Sara Ahmad Kelayeh
Cyrus Ghotbi
Vahid Taghikhani
Amir Jalili
spellingShingle Sara Ahmad Kelayeh
Cyrus Ghotbi
Vahid Taghikhani
Amir Jalili
Correlation of Viscosity of Aqueous Solutions of Alkanolamine Mixtures Based on the Eyring's Theory and Wong-Sandler Mixing Rule
Iranian Journal of Chemistry & Chemical Engineering
ws mixing rule
viscosity models
equation of state
nrtl
wilson
author_facet Sara Ahmad Kelayeh
Cyrus Ghotbi
Vahid Taghikhani
Amir Jalili
author_sort Sara Ahmad Kelayeh
title Correlation of Viscosity of Aqueous Solutions of Alkanolamine Mixtures Based on the Eyring's Theory and Wong-Sandler Mixing Rule
title_short Correlation of Viscosity of Aqueous Solutions of Alkanolamine Mixtures Based on the Eyring's Theory and Wong-Sandler Mixing Rule
title_full Correlation of Viscosity of Aqueous Solutions of Alkanolamine Mixtures Based on the Eyring's Theory and Wong-Sandler Mixing Rule
title_fullStr Correlation of Viscosity of Aqueous Solutions of Alkanolamine Mixtures Based on the Eyring's Theory and Wong-Sandler Mixing Rule
title_full_unstemmed Correlation of Viscosity of Aqueous Solutions of Alkanolamine Mixtures Based on the Eyring's Theory and Wong-Sandler Mixing Rule
title_sort correlation of viscosity of aqueous solutions of alkanolamine mixtures based on the eyring's theory and wong-sandler mixing rule
publisher Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
series Iranian Journal of Chemistry & Chemical Engineering
issn 1021-9986
1021-9986
publishDate 2013-06-01
description A viscosity model, based on Eyring’s absolute rate theory combined with a cubic PR equation of state and Wong-Sandler mixing rule, has been proposed in order to correlate viscosities of aqueous solutions of alkanolamine mixtures at atmospheric pressure and different temperatures. In the proposed method, the energy and size parameters in studied Equation of State (EoS) have been obtained using the Wong – Sandler (WS) mixing rule combined with the NRTL and Wilson Gibbs equations. The NRTL and Wilson parameters for aqueous solutions of alkanolamine mixtures have been correlated using measured viscosity data at atmospheric pressure and different temperatures. The overall average deviation between the experimental and calculated viscosities of studied aqueous solutions of alkanolamine mixtures using Wilson model is 0.92%.
topic ws mixing rule
viscosity models
equation of state
nrtl
wilson
url http://www.ijcce.ac.ir/article_5863_d4cf70090b6f82b504893d1e66d9f13a.pdf
work_keys_str_mv AT saraahmadkelayeh correlationofviscosityofaqueoussolutionsofalkanolaminemixturesbasedontheeyringstheoryandwongsandlermixingrule
AT cyrusghotbi correlationofviscosityofaqueoussolutionsofalkanolaminemixturesbasedontheeyringstheoryandwongsandlermixingrule
AT vahidtaghikhani correlationofviscosityofaqueoussolutionsofalkanolaminemixturesbasedontheeyringstheoryandwongsandlermixingrule
AT amirjalili correlationofviscosityofaqueoussolutionsofalkanolaminemixturesbasedontheeyringstheoryandwongsandlermixingrule
_version_ 1724584631788896256