Benzyne arylation of oxathiane glycosyl donors

The arylation of bicyclic oxathiane glycosyl donors has been achieved using benzyne generated in situ from 1-aminobenzotriazole (1-ABT) and lead tetraacetate. Following sulfur arylation, glycosylation of acetate ions proceeded with high levels of stereoselectivity to afford α-glycosyl acetates in a...

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Bibliographic Details
Main Authors: Martin A. Fascione, W. Bruce Turnbull
Format: Article
Language:English
Published: Beilstein-Institut 2010-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.6.19

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