Guanidinium hexaaquazinc(II) bis[tris(3-carboxypyridine-2-carboxylato)zincate]
In the title molecular salt, (CH6N3)1.30[Zn(H2O)6]0.35[Zn(C7H4NO4)3]2, the ZnII atom (site symmetry 3) in the anion is coordinated by three N,O-bidentate 3-carboxypyridine-2-carboxylate monoanions to generate a fac-ZnN3O3 octahedral coordination geometry. The guanidinium cation (the C atom has site...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2012-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681202987X |
| Summary: | In the title molecular salt, (CH6N3)1.30[Zn(H2O)6]0.35[Zn(C7H4NO4)3]2, the ZnII atom (site symmetry 3) in the anion is coordinated by three N,O-bidentate 3-carboxypyridine-2-carboxylate monoanions to generate a fac-ZnN3O3 octahedral coordination geometry. The guanidinium cation (the C atom has site symmetry 3) and the octahedral hexaaquazinc(II) dication (the Zn2+ cation has site symmetry -3) are occupationally disordered in a 1.30:0.35 ratio. In the crystal, the components are linked by O—H...O and N—H...O hydrogen bonds to generate infinite (001) sheets. Weak aromatic π–π stacking [centroid–centroid distance = 3.797 (8) Å] is also observed in the crystal. |
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| ISSN: | 1600-5368 |