Triaqua-1κO,2κ2O-bis(2,2′-bipyridine)-1κ2N,N′;2κ2N,N′-chlorido-1κCl-μ-terephthalato-1:2κ2O1:O4-dicopper(II) nitrate monohydrate

Triaqua-1κO,2κ2O-bis(2,2′-bipyridine)-1κ2N,N′;2κ2N,N′-chlorido-1κCl-μ-terephthalato-1:2κ2O1:O4-dicopper(II) nitrate monohydrate

In the binuclear title compound, [Cu2(C8H4O4)Cl(C10H8N2)2(H2O)3]NO3·H2O, the two crystallographically independent CuII ions have similar coordination environments. One of the CuII ions has a square-pyramidal arrangement, which is defined by a water molecule occupying the apical position...

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Main Authors: Yang Liu, Yong-Lan Feng, Dai-Zhi Kuang
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812019848
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spelling doaj-2834b9af00c7477d92e9c51dfe453a252020-11-25T01:57:48ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m746m74710.1107/S1600536812019848Triaqua-1κO,2κ2O-bis(2,2′-bipyridine)-1κ2N,N′;2κ2N,N′-chlorido-1κCl-μ-terephthalato-1:2κ2O1:O4-dicopper(II) nitrate monohydrateYang LiuYong-Lan FengDai-Zhi KuangIn the binuclear title compound, [Cu2(C8H4O4)Cl(C10H8N2)2(H2O)3]NO3·H2O, the two crystallographically independent CuII ions have similar coordination environments. One of the CuII ions has a square-pyramidal arrangement, which is defined by a water molecule occupying the apical position, with the equatorial ligators consisting of two N atoms from a 2,2′-bipyridine molecule, one carboxylate O atom from a terephthalate ligand and one O atom from a water molecule. The other CuII ion has a similar coordination environment, except that the apical position is occupied by a chloride ligand instead of a water molecule. An O—H...O and O—H...Cl hydrogen-bonded three-dimensional network is formed between the components.http://scripts.iucr.org/cgi-bin/paper?S1600536812019848
collection DOAJ
language English
format Article
sources DOAJ
author Yang Liu
Yong-Lan Feng
Dai-Zhi Kuang
spellingShingle Yang Liu
Yong-Lan Feng
Dai-Zhi Kuang
Triaqua-1κO,2κ2O-bis(2,2′-bipyridine)-1κ2N,N′;2κ2N,N′-chlorido-1κCl-μ-terephthalato-1:2κ2O1:O4-dicopper(II) nitrate monohydrate
Acta Crystallographica Section E
author_facet Yang Liu
Yong-Lan Feng
Dai-Zhi Kuang
author_sort Yang Liu
title Triaqua-1κO,2κ2O-bis(2,2′-bipyridine)-1κ2N,N′;2κ2N,N′-chlorido-1κCl-μ-terephthalato-1:2κ2O1:O4-dicopper(II) nitrate monohydrate
title_short Triaqua-1κO,2κ2O-bis(2,2′-bipyridine)-1κ2N,N′;2κ2N,N′-chlorido-1κCl-μ-terephthalato-1:2κ2O1:O4-dicopper(II) nitrate monohydrate
title_full Triaqua-1κO,2κ2O-bis(2,2′-bipyridine)-1κ2N,N′;2κ2N,N′-chlorido-1κCl-μ-terephthalato-1:2κ2O1:O4-dicopper(II) nitrate monohydrate
title_fullStr Triaqua-1κO,2κ2O-bis(2,2′-bipyridine)-1κ2N,N′;2κ2N,N′-chlorido-1κCl-μ-terephthalato-1:2κ2O1:O4-dicopper(II) nitrate monohydrate
title_full_unstemmed Triaqua-1κO,2κ2O-bis(2,2′-bipyridine)-1κ2N,N′;2κ2N,N′-chlorido-1κCl-μ-terephthalato-1:2κ2O1:O4-dicopper(II) nitrate monohydrate
title_sort triaqua-1κo,2κ2o-bis(2,2′-bipyridine)-1κ2n,n′;2κ2n,n′-chlorido-1κcl-μ-terephthalato-1:2κ2o1:o4-dicopper(ii) nitrate monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description In the binuclear title compound, [Cu2(C8H4O4)Cl(C10H8N2)2(H2O)3]NO3·H2O, the two crystallographically independent CuII ions have similar coordination environments. One of the CuII ions has a square-pyramidal arrangement, which is defined by a water molecule occupying the apical position, with the equatorial ligators consisting of two N atoms from a 2,2′-bipyridine molecule, one carboxylate O atom from a terephthalate ligand and one O atom from a water molecule. The other CuII ion has a similar coordination environment, except that the apical position is occupied by a chloride ligand instead of a water molecule. An O—H...O and O—H...Cl hydrogen-bonded three-dimensional network is formed between the components.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812019848
work_keys_str_mv AT yangliu triaqua1amp954o2amp9542obis22amp8242bipyridine1amp9542nnamp82422amp9542nnamp8242chlorido1amp954clamp956terephthalato12amp9542o1o4dicopperiinitratemonohydrate
AT yonglanfeng triaqua1amp954o2amp9542obis22amp8242bipyridine1amp9542nnamp82422amp9542nnamp8242chlorido1amp954clamp956terephthalato12amp9542o1o4dicopperiinitratemonohydrate
AT daizhikuang triaqua1amp954o2amp9542obis22amp8242bipyridine1amp9542nnamp82422amp9542nnamp8242chlorido1amp954clamp956terephthalato12amp9542o1o4dicopperiinitratemonohydrate
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