Ti-V-C-Based Alloy with a FCC Lattice Structure for Hydrogen Storage

• Main Authors: Bo Li, Liqing He, Jianding Li, Hai-Wen Li, Zhouguang Lu, Huaiyu Shao
• Format: Article
• Language: English
• Published: MDPI AG 2019-02-01
• Series: Molecules
• Subjects: mechanical alloying; metals and alloys; crystal structure; hydrogen absorbing materials
• Online Access: https://www.mdpi.com/1420-3049/24/3/552
• ISSN: 1420-3049

Here we report a Ti₅₀V₅₀-10 wt.% C alloy with a unique lattice and microstructure for hydrogen storage development. Different from a traditionally synthesized Ti₅₀V₅₀ alloy prepared by a melting method and having a body-centered cubic (BCC) structure, this Ti₅₀V₅₀-C alloy synthesized by a mechanical alloying method is with a face-centered cubic (FCC) structure (space group: <i>Fm-3m</i> No. 225). The crystalline size is 60 nm. This alloy may directly absorb hydrogen near room temperature without any activation process. Mechanisms of the good kinetics from lattice and microstructure aspects were discussed. Findings reported here may indicate a new possibility in the development of future hydrogen storage materials.