| Summary: | The present research focuses on the investigation of an in situ hydrogen charging effect during Crack Tip Opening Displacement testing (CTOD) on the fracture toughness properties of X65 pipeline steel. This grade of steel belongs to the broader category of High Strength Low Alloy Steels (HSLA), and its microstructure consists of equiaxed ferritic and bainitic grains with a low volume fraction of degenerated pearlite islands. The studied X65 steel specimens were extracted from pipes with 19.15 mm wall thickness. The fracture toughness parameters were determined after imposing the fatigue pre-cracked specimens on air, on a specific electrolytic cell under a slow strain rate bending loading (according to ASTM G147-98, BS7448, and ISO12135 standards). Concerning the results of this study, in the first phase the hydrogen cations’ penetration depth, the diffusion coefficient of molecular and atomic hydrogen, and the surficial density of blisters were determined. Next, the characteristic parameters related to fracture toughness (such as J, KQ, CTOD<sub>el</sub>, CTOD<sub>pl</sub>) were calculated by the aid of the Force-Crack Mouth Open Displacement curves and the relevant analytical equations.
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