μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate

μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate

In the binuclear title compound, [Mo2(C12H15N4O2)2Cl2O3]·H2O, the complex molecules have approximate C2 symmetry. Both MoV atoms have a distorted octahedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the...

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Main Authors: Amalija Golobič, Boris Čeh
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810045393
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spelling doaj-2771415f58c3483f934dd939fa8dddda2020-11-25T02:15:23ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1648m164910.1107/S1600536810045393μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrateAmalija GolobičBoris ČehIn the binuclear title compound, [Mo2(C12H15N4O2)2Cl2O3]·H2O, the complex molecules have approximate C2 symmetry. Both MoV atoms have a distorted octahedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the MoV atom via an N2O donor set. The water molecule bridges two complex molecules, forming O—H...O and O—H...Cl hydrogen bonds to the acetate group and to the chloride ligands. http://scripts.iucr.org/cgi-bin/paper?S1600536810045393
collection DOAJ
language English
format Article
sources DOAJ
author Amalija Golobič
Boris Čeh
spellingShingle Amalija Golobič
Boris Čeh
μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate
Acta Crystallographica Section E
author_facet Amalija Golobič
Boris Čeh
author_sort Amalija Golobič
title μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate
title_short μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate
title_full μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate
title_fullStr μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate
title_full_unstemmed μ-Oxido-bis{[2,2-bis(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ3N2,O,N2′]chloridooxidomolybdenum(V)} monohydrate
title_sort μ-oxido-bis{[2,2-bis(3,5-dimethyl-1h-pyrazol-1-yl)acetato-κ3n2,o,n2′]chloridooxidomolybdenum(v)} monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description In the binuclear title compound, [Mo2(C12H15N4O2)2Cl2O3]·H2O, the complex molecules have approximate C2 symmetry. Both MoV atoms have a distorted octahedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the MoV atom via an N2O donor set. The water molecule bridges two complex molecules, forming O—H...O and O—H...Cl hydrogen bonds to the acetate group and to the chloride ligands.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810045393
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AT borisamp268eh amp956oxidobis22bis35dimethyl1hpyrazol1ylacetatoamp9543n2on2amp8242chloridooxidomolybdenumvmonohydrate
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