Effect of Sodium Phosphate and Calcium Nitrate Sealing Treatment on Microstructure and Corrosion Resistance of Wire Arc Sprayed Aluminum Coatings

• Main Authors: Han-Seung Lee, Ashutosh Kumar, Soumen Mandal, Jitendra Kumar Singh, Fahid ASLAM, Rayed Alyousef, Hisham Albduljabbar
• Format: Article
• Language: English
• Published: MDPI AG 2020-01-01
• Series: Coatings
• Subjects: aluminum; steel; coating; corrosion; cathodic protection; arc thermal spray; scanning electron microscopy; x-ray diffraction
• Online Access: https://www.mdpi.com/2079-6412/10/1/33

Aluminum coating was deposited by arc thermal spraying process onto the steel substrate for the corrosion protection in aggressive environment. However, the arc thermal sprayed coating possesses defects in the coating. Thus, it is important to reduce the defects and enhance the corrosion resistance properties of the deposited coating using post-treatment. In the present study, we have used different concentrations of sodium phosphate mono basic (NaH₂PO₄) with 0.1 molar (M) calcium nitrate [Ca(NO₃)₂] as post-treatment solution to fill out the defects of the Al coating. It was observed by scanning electron microscopy (SEM) that 1 M NaH₂PO₄ with 0.1 M Ca(NO₃)₂ treated sample exhibited 71% reduction in defects compared to as coated samples. X-ray diffraction (XRD) was performed to determine the phases formed on the coating surface after treatments. XRD confirms the formation of sodium aluminum hydrogen phosphate (Na₃Al(OH)(HPO₄)(PO₄)) and brushite (Ca(HPO₄)(H₂O)₂) as composite oxides on the Al coating. Electrochemical results show that 0.5 M NaH₂PO₄ with 0.1 M Ca(NO₃)₂ treated sample has exhibited the highest charge transfer resistance and the lowest corrosion current density after 89 days of exposure in 3.5 wt.% NaCl solution. The enhancement in corrosion resistance of 0.5 M NaH₂PO₄ with 0.1 M Ca(NO₃)₂ treated sample attributed to the formation of adherent, sparingly soluble, and stable corrosion products. The volume fraction result of the corrosion products formed on 0.5 M NaH₂PO₄ with 0.1 M Ca(NO₃)₂ treated sample after 89 days of exposure in 3.5 wt.% NaCl using XRD confirms the highest amount of Bayerite (α-Al(OH)₃) deposition, thus, the corrosion rate of this sample was the lowest.