1,4-Di-tert-butyl (2R,3R)-2-({(2E)-3-[4-(acetyloxy)phenyl]prop-2-enoyl}oxy)-3-hydroxybutanedioate
The title compound, C23H30O9, has an approximate T-shape with the tert-butyl ester groups lying either side of the benzene ring. The acetyl group is almost perpendicular to the benzene ring to which it is connected [C—C—O—C torsion angle = −106...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681200236X |
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Article |
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doaj-2631f1f630e74008b467dda065cd0f1a2020-11-25T02:15:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-02-01682o509o51010.1107/S160053681200236X1,4-Di-tert-butyl (2R,3R)-2-({(2E)-3-[4-(acetyloxy)phenyl]prop-2-enoyl}oxy)-3-hydroxybutanedioateJosh L. HixsonDennis K. TaylorSeik Weng NgEdward R. T. TiekinkThe title compound, C23H30O9, has an approximate T-shape with the tert-butyl ester groups lying either side of the benzene ring. The acetyl group is almost perpendicular to the benzene ring to which it is connected [C—C—O—C torsion angle = −106.7 (3)°]. The conformation about the C=C double bond [1.331 (4) Å] is E. Linear supramolecular chains along the a axis mediated by hydroxy–carbonyl O—H...O hydrogen bonds feature in the crystal packing. The same H atom is also involved in an intramolecular O—H...O interaction.http://scripts.iucr.org/cgi-bin/paper?S160053681200236X |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Josh L. Hixson Dennis K. Taylor Seik Weng Ng Edward R. T. Tiekink |
| spellingShingle |
Josh L. Hixson Dennis K. Taylor Seik Weng Ng Edward R. T. Tiekink 1,4-Di-tert-butyl (2R,3R)-2-({(2E)-3-[4-(acetyloxy)phenyl]prop-2-enoyl}oxy)-3-hydroxybutanedioate Acta Crystallographica Section E |
| author_facet |
Josh L. Hixson Dennis K. Taylor Seik Weng Ng Edward R. T. Tiekink |
| author_sort |
Josh L. Hixson |
| title |
1,4-Di-tert-butyl (2R,3R)-2-({(2E)-3-[4-(acetyloxy)phenyl]prop-2-enoyl}oxy)-3-hydroxybutanedioate |
| title_short |
1,4-Di-tert-butyl (2R,3R)-2-({(2E)-3-[4-(acetyloxy)phenyl]prop-2-enoyl}oxy)-3-hydroxybutanedioate |
| title_full |
1,4-Di-tert-butyl (2R,3R)-2-({(2E)-3-[4-(acetyloxy)phenyl]prop-2-enoyl}oxy)-3-hydroxybutanedioate |
| title_fullStr |
1,4-Di-tert-butyl (2R,3R)-2-({(2E)-3-[4-(acetyloxy)phenyl]prop-2-enoyl}oxy)-3-hydroxybutanedioate |
| title_full_unstemmed |
1,4-Di-tert-butyl (2R,3R)-2-({(2E)-3-[4-(acetyloxy)phenyl]prop-2-enoyl}oxy)-3-hydroxybutanedioate |
| title_sort |
1,4-di-tert-butyl (2r,3r)-2-({(2e)-3-[4-(acetyloxy)phenyl]prop-2-enoyl}oxy)-3-hydroxybutanedioate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2012-02-01 |
| description |
The title compound, C23H30O9, has an approximate T-shape with the tert-butyl ester groups lying either side of the benzene ring. The acetyl group is almost perpendicular to the benzene ring to which it is connected [C—C—O—C torsion angle = −106.7 (3)°]. The conformation about the C=C double bond [1.331 (4) Å] is E. Linear supramolecular chains along the a axis mediated by hydroxy–carbonyl O—H...O hydrogen bonds feature in the crystal packing. The same H atom is also involved in an intramolecular O—H...O interaction. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S160053681200236X |
| work_keys_str_mv |
AT joshlhixson 14ditertbutyl2r3r22e34acetyloxyphenylprop2enoyloxy3hydroxybutanedioate AT dennisktaylor 14ditertbutyl2r3r22e34acetyloxyphenylprop2enoyloxy3hydroxybutanedioate AT seikwengng 14ditertbutyl2r3r22e34acetyloxyphenylprop2enoyloxy3hydroxybutanedioate AT edwardrttiekink 14ditertbutyl2r3r22e34acetyloxyphenylprop2enoyloxy3hydroxybutanedioate |
| _version_ |
1724897923532062720 |