Stabilization of a Clay Soil Using Cementing Material from Spent Refractories and Ground-Granulated Blast Furnace Slag

Nowadays, huge amounts of refractory materials are generated around the world. The majority of them lack valorization methods. This study analyzes the ability of a doloma and two magnesia spent refractory wastes as soil stabilizers on their own, as well as when combined with Ground-Granulated Blast...

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Main Authors: Andres Seco, Jesus María del Castillo, Sandra Espuelas, Sara Marcelino-Sadaba, Benat Garcia
Format: Article
Language:English
Published: MDPI AG 2021-03-01
Series:Sustainability
Subjects:
Online Access:https://www.mdpi.com/2071-1050/13/6/3015
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spelling doaj-260ba1c652684b2c81210ff70bb188ac2021-03-11T00:01:47ZengMDPI AGSustainability2071-10502021-03-01133015301510.3390/su13063015Stabilization of a Clay Soil Using Cementing Material from Spent Refractories and Ground-Granulated Blast Furnace SlagAndres Seco0Jesus María del Castillo1Sandra Espuelas2Sara Marcelino-Sadaba3Benat Garcia4Institute of Smart Cities, Public University of Navarre, 31006 Pamplona, SpainInstitute of Smart Cities, Public University of Navarre, 31006 Pamplona, SpainInstitute of Smart Cities, Public University of Navarre, 31006 Pamplona, SpainDepartment of Engineering, Public University of Navarre, 31006 Pamplona, SpainDepartment of Mining and Metallurgical Engineering and Materials Science, Faculty of Engineering Vitoria-Gasteiz, University of Basque Country UPV/EHU, 01006 Vitoria-Gasteiz, SpainNowadays, huge amounts of refractory materials are generated around the world. The majority of them lack valorization methods. This study analyzes the ability of a doloma and two magnesia spent refractory wastes as soil stabilizers on their own, as well as when combined with Ground-Granulated Blast Furnace Slags (GGBS). These materials showed a limited ability for the soil’s plasticity modification from a plasticity index of 15.6 to a minimum of 12.7. The high pH of the additives increased the soil’s pH from 7.88 to values in the range of 10.94–11.25 before the 28 days, allowing the development of the pozzolanic reactions. Unconfined compressive strength (UCS) increased along the curing time, reaching a maximum value of 5.68 MPa after 90 days. Based on the UCS, the optimum refractory GGBS ratios oscillate between 30:70 and 50:50. The UCS values after soaking samples reduced the unsoaked results between 68.70% to 94.41%. The binders considered showed a low effect against the soil swelling and the lack of delayed expansive effects because of the MgO hydration. Finally, X Ray Diffraction (XRD) tests showed that the stabilization only slightly modified the combinations of mineralogy and the formation of Magnesium Silicate Hydrate (MSH) gels.https://www.mdpi.com/2071-1050/13/6/3015spent refractory materialswaste valorizationsoil stabilizationbinderssustainable construction
collection DOAJ
language English
format Article
sources DOAJ
author Andres Seco
Jesus María del Castillo
Sandra Espuelas
Sara Marcelino-Sadaba
Benat Garcia
spellingShingle Andres Seco
Jesus María del Castillo
Sandra Espuelas
Sara Marcelino-Sadaba
Benat Garcia
Stabilization of a Clay Soil Using Cementing Material from Spent Refractories and Ground-Granulated Blast Furnace Slag
Sustainability
spent refractory materials
waste valorization
soil stabilization
binders
sustainable construction
author_facet Andres Seco
Jesus María del Castillo
Sandra Espuelas
Sara Marcelino-Sadaba
Benat Garcia
author_sort Andres Seco
title Stabilization of a Clay Soil Using Cementing Material from Spent Refractories and Ground-Granulated Blast Furnace Slag
title_short Stabilization of a Clay Soil Using Cementing Material from Spent Refractories and Ground-Granulated Blast Furnace Slag
title_full Stabilization of a Clay Soil Using Cementing Material from Spent Refractories and Ground-Granulated Blast Furnace Slag
title_fullStr Stabilization of a Clay Soil Using Cementing Material from Spent Refractories and Ground-Granulated Blast Furnace Slag
title_full_unstemmed Stabilization of a Clay Soil Using Cementing Material from Spent Refractories and Ground-Granulated Blast Furnace Slag
title_sort stabilization of a clay soil using cementing material from spent refractories and ground-granulated blast furnace slag
publisher MDPI AG
series Sustainability
issn 2071-1050
publishDate 2021-03-01
description Nowadays, huge amounts of refractory materials are generated around the world. The majority of them lack valorization methods. This study analyzes the ability of a doloma and two magnesia spent refractory wastes as soil stabilizers on their own, as well as when combined with Ground-Granulated Blast Furnace Slags (GGBS). These materials showed a limited ability for the soil’s plasticity modification from a plasticity index of 15.6 to a minimum of 12.7. The high pH of the additives increased the soil’s pH from 7.88 to values in the range of 10.94–11.25 before the 28 days, allowing the development of the pozzolanic reactions. Unconfined compressive strength (UCS) increased along the curing time, reaching a maximum value of 5.68 MPa after 90 days. Based on the UCS, the optimum refractory GGBS ratios oscillate between 30:70 and 50:50. The UCS values after soaking samples reduced the unsoaked results between 68.70% to 94.41%. The binders considered showed a low effect against the soil swelling and the lack of delayed expansive effects because of the MgO hydration. Finally, X Ray Diffraction (XRD) tests showed that the stabilization only slightly modified the combinations of mineralogy and the formation of Magnesium Silicate Hydrate (MSH) gels.
topic spent refractory materials
waste valorization
soil stabilization
binders
sustainable construction
url https://www.mdpi.com/2071-1050/13/6/3015
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