| Summary: | A novel alumina-assisted treatment process was proposed to manufacture fully densified and perfectly spherical WC-Co particles for thermal spraying applications. In as-sprayed coating, the decarburization phenomenon common in previous studies was almost entirely eliminated, and a unique binder structure with nanocrystalline and amorphous Co co-existing was obtained. Owing to the strengthening effects of nanocrystalline Co and WC/Co interfacial bonding, the wear resistance of the new coating was 4 times higher than that of the conventional coating prepared with a porous feedstock. Instead of plastic deformation, interface fracture and micro-cutting that mainly occurred in conventional WC-based coatings, fracture of WC grains and subsequent oxidation dominated wear failure of the new WC-Co coating. The present work opens up new opportunities for the fabrication of dense ceramic-metal composite particles and wear-resistance enhancement of cermet coatings.
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