5-[(E)-2-Fluorobenzylidene]-8-(2-fluorophenyl)-2-hydroxy-10-methyl-3,10-diazahexacyclo[10.7.1.13,7.02,11.07,11.016,20]henicosa-1(20),12,14,16,18-pentaen-6-one

In the title compound, C33H26F2N2O2, the piperidone ring adopts a half-chair conformation and the pyrrolidine rings adopt half-chair and envelope conformations. The two benzene rings make dihedral angles of 29.58 (5) and 76.33 (5)° with the mean plane of the...

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Bibliographic Details
Main Authors: Hoong-Kun Fun, Chin Sing Yeap, Hasnah Osman, Raju Suresh Kumar
Format: Article
Language:English
Published: International Union of Crystallography 2011-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810052815
Description
Summary:In the title compound, C33H26F2N2O2, the piperidone ring adopts a half-chair conformation and the pyrrolidine rings adopt half-chair and envelope conformations. The two benzene rings make dihedral angles of 29.58 (5) and 76.33 (5)° with the mean plane of the 1,2-dihydroacenaphthylene unit. An intramolecular O—H...N hydrogen bond helps to stabilize the molecular structure. In the crystal, intermolecular C—H...F hydrogen bonds link the molecules into [010] chains. Weak C—H...π interactions are also observed.
ISSN:1600-5368