Bis(N-nitroso-N-pentylhydroxylaminato-κ2O,O′)copper(II)

Bis(N-nitroso-N-pentylhydroxylaminato-κ2O,O′)copper(II)

In the centrosymmetric title compound, [Cu(C5H11N2O2)2], the Cu2+ ion, located on an inversion centre (Wyckoff position 2b), is in a square-planar environment, surounded by four O atoms of the N—O groups of two N-nitroso-N-pentylhydroxylaminate ligands [Cu—O = 1.9042 (17) and 1.9095 (16) Å]. The hyd...

Full description

Bibliographic Details
Main Authors: Ali Sheikh Bostanabad, Olga Kovalchukova, Svetlana Strashnova, Adam Stash, Igor Zyuzin
Format: Article
Language:English
Published: International Union of Crystallography 2014-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814004978
id doaj-24d3acff3dec40ab9b085726e7cea4b8
record_format Article
spelling doaj-24d3acff3dec40ab9b085726e7cea4b82020-11-25T01:35:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-04-01704m137m13810.1107/S1600536814004978pj2009Bis(N-nitroso-N-pentylhydroxylaminato-κ2O,O′)copper(II)Ali Sheikh Bostanabad0Olga Kovalchukova1Svetlana Strashnova2Adam Stash3Igor Zyuzin4Peoples' Friendship University of Russia, 6 Miklukho-Mallaya, 117198 Moscow, Russian FederationPeoples' Friendship University of Russia, 6 Miklukho-Mallaya, 117198 Moscow, Russian FederationPeoples' Friendship University of Russia, 6 Miklukho-Mallaya, 117198 Moscow, Russian FederationKarpov Institute of Physical Chemistry, 10 Vorontsovo Pole, 105064 Moscow, Russian FederationThe Institute of Problems of Chemical Physics of the Russian Academy of Sciences (IPCP RAS), Academician Semenov Avenue 1, Chernogolovka, Moscow region, 142432, Russian FederationIn the centrosymmetric title compound, [Cu(C5H11N2O2)2], the Cu2+ ion, located on an inversion centre (Wyckoff position 2b), is in a square-planar environment, surounded by four O atoms of the N—O groups of two N-nitroso-N-pentylhydroxylaminate ligands [Cu—O = 1.9042 (17) and 1.9095 (16) Å]. The hydroxylaminate monoanions are bidentate chelating ligands. The Cu2+ cations form stacks along [010], with intermolecular Cu...N contacts of 3.146 (2) and 3.653 (2) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536814004978
collection DOAJ
language English
format Article
sources DOAJ
author Ali Sheikh Bostanabad
Olga Kovalchukova
Svetlana Strashnova
Adam Stash
Igor Zyuzin
spellingShingle Ali Sheikh Bostanabad
Olga Kovalchukova
Svetlana Strashnova
Adam Stash
Igor Zyuzin
Bis(N-nitroso-N-pentylhydroxylaminato-κ2O,O′)copper(II)
Acta Crystallographica Section E
author_facet Ali Sheikh Bostanabad
Olga Kovalchukova
Svetlana Strashnova
Adam Stash
Igor Zyuzin
author_sort Ali Sheikh Bostanabad
title Bis(N-nitroso-N-pentylhydroxylaminato-κ2O,O′)copper(II)
title_short Bis(N-nitroso-N-pentylhydroxylaminato-κ2O,O′)copper(II)
title_full Bis(N-nitroso-N-pentylhydroxylaminato-κ2O,O′)copper(II)
title_fullStr Bis(N-nitroso-N-pentylhydroxylaminato-κ2O,O′)copper(II)
title_full_unstemmed Bis(N-nitroso-N-pentylhydroxylaminato-κ2O,O′)copper(II)
title_sort bis(n-nitroso-n-pentylhydroxylaminato-κ2o,o′)copper(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-04-01
description In the centrosymmetric title compound, [Cu(C5H11N2O2)2], the Cu2+ ion, located on an inversion centre (Wyckoff position 2b), is in a square-planar environment, surounded by four O atoms of the N—O groups of two N-nitroso-N-pentylhydroxylaminate ligands [Cu—O = 1.9042 (17) and 1.9095 (16) Å]. The hydroxylaminate monoanions are bidentate chelating ligands. The Cu2+ cations form stacks along [010], with intermolecular Cu...N contacts of 3.146 (2) and 3.653 (2) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536814004978
work_keys_str_mv AT alisheikhbostanabad bisnnitrosonpentylhydroxylaminatok2oocopperii
AT olgakovalchukova bisnnitrosonpentylhydroxylaminatok2oocopperii
AT svetlanastrashnova bisnnitrosonpentylhydroxylaminatok2oocopperii
AT adamstash bisnnitrosonpentylhydroxylaminatok2oocopperii
AT igorzyuzin bisnnitrosonpentylhydroxylaminatok2oocopperii
_version_ 1725065772722552832

Similar Items