Bis(N-nitroso-N-pentylhydroxylaminato-κ2O,O′)copper(II)

Bis(N-nitroso-N-pentylhydroxylaminato-κ2O,O′)copper(II)

In the centrosymmetric title compound, [Cu(C5H11N2O2)2], the Cu2+ ion, located on an inversion centre (Wyckoff position 2b), is in a square-planar environment, surounded by four O atoms of the N—O groups of two N-nitroso-N-pentylhydroxylaminate ligands [Cu—O = 1.9042 (17) and 1.9095 (16) Å]. The hyd...

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Bibliographic Details
Main Authors: Ali Sheikh Bostanabad, Olga Kovalchukova, Svetlana Strashnova, Adam Stash, Igor Zyuzin
Format: Article
Language:English
Published: International Union of Crystallography 2014-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814004978
Description
Summary:In the centrosymmetric title compound, [Cu(C5H11N2O2)2], the Cu2+ ion, located on an inversion centre (Wyckoff position 2b), is in a square-planar environment, surounded by four O atoms of the N—O groups of two N-nitroso-N-pentylhydroxylaminate ligands [Cu—O = 1.9042 (17) and 1.9095 (16) Å]. The hydroxylaminate monoanions are bidentate chelating ligands. The Cu2+ cations form stacks along [010], with intermolecular Cu...N contacts of 3.146 (2) and 3.653 (2) Å.
ISSN:1600-5368

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