Solvent free interactions in contact pairs of molecules of biological interest: Laser spectroscopic and electrospray mass spectrometric studies
A laser spectroscopic and mass spectrometric study of ionic and molecular clusters of biological interest is reported. The molecules of interest and their aggregates were generated in a supersonic beam and analyzed by mass resolved resonant two photon absorption and ionization (R2PI) and by collisio...
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Series: | International Journal of Photoenergy |
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doaj-241abd3eedf2405fa47308ef9e5c77cf2020-11-25T00:15:10ZengHindawi LimitedInternational Journal of Photoenergy1110-662X2004-01-0161172110.1155/S1110662X04000030Solvent free interactions in contact pairs of molecules of biological interest: Laser spectroscopic and electrospray mass spectrometric studiesD. Scuderi0A. Paladini1M. Satta2D. Catone3F. Rondino4A. Filippi5S. Piccirillo6M. Speranza7A. Giardini Guidoni8Dipartimento di Chimica, Università di Roma “La Sapienza”, pl. A. Moro 5, Roma I-00185, ItalyDipartimento di Chimica, Università di Roma “La Sapienza”, pl. A. Moro 5, Roma I-00185, ItalyCNR-IMIP (sezione Istituto Materiali Speciali), Tito Scalo (Pz), I-85050, ItalyDipartimento di Chimica, Università di Roma “La Sapienza”, pl. A. Moro 5, Roma I-00185, ItalyDipartimento di Chimica, Università di Roma “La Sapienza”, pl. A. Moro 5, Roma I-00185, ItalyFacoltà di Farmacia, Dipartimento di Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Università di Roma “La Sapienza”, pl. A. Moro 5, Roma I-00185, ItalyUniversità di Roma “Tor Vergata”, Dipartimento di Scienze e Tecnologie Chimiche, Via della Ricerca Scientifica, Rome I-00133, ItalyFacoltà di Farmacia, Dipartimento di Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Università di Roma “La Sapienza”, pl. A. Moro 5, Roma I-00185, ItalyDipartimento di Chimica, Università di Roma “La Sapienza”, pl. A. Moro 5, Roma I-00185, ItalyA laser spectroscopic and mass spectrometric study of ionic and molecular clusters of biological interest is reported. The molecules of interest and their aggregates were generated in a supersonic beam and analyzed by mass resolved resonant two photon absorption and ionization (R2PI) and by collision induced mass spectrometry (CID-MS). The absence of the solvent allows to study these systems in the isolated state free of undesired solvent effects which may level off the differences in their properties. The gas phase results have been compared to theoretical estimates of the structure and stability of the systems under investigation.http://dx.doi.org/10.1155/S1110662X04000030 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
D. Scuderi A. Paladini M. Satta D. Catone F. Rondino A. Filippi S. Piccirillo M. Speranza A. Giardini Guidoni |
spellingShingle |
D. Scuderi A. Paladini M. Satta D. Catone F. Rondino A. Filippi S. Piccirillo M. Speranza A. Giardini Guidoni Solvent free interactions in contact pairs of molecules of biological interest: Laser spectroscopic and electrospray mass spectrometric studies International Journal of Photoenergy |
author_facet |
D. Scuderi A. Paladini M. Satta D. Catone F. Rondino A. Filippi S. Piccirillo M. Speranza A. Giardini Guidoni |
author_sort |
D. Scuderi |
title |
Solvent free interactions in contact pairs of molecules of biological interest: Laser spectroscopic and
electrospray mass spectrometric studies |
title_short |
Solvent free interactions in contact pairs of molecules of biological interest: Laser spectroscopic and
electrospray mass spectrometric studies |
title_full |
Solvent free interactions in contact pairs of molecules of biological interest: Laser spectroscopic and
electrospray mass spectrometric studies |
title_fullStr |
Solvent free interactions in contact pairs of molecules of biological interest: Laser spectroscopic and
electrospray mass spectrometric studies |
title_full_unstemmed |
Solvent free interactions in contact pairs of molecules of biological interest: Laser spectroscopic and
electrospray mass spectrometric studies |
title_sort |
solvent free interactions in contact pairs of molecules of biological interest: laser spectroscopic and
electrospray mass spectrometric studies |
publisher |
Hindawi Limited |
series |
International Journal of Photoenergy |
issn |
1110-662X |
publishDate |
2004-01-01 |
description |
A laser spectroscopic and mass spectrometric study of ionic and molecular clusters of biological
interest is reported. The molecules of interest and their aggregates were generated in a supersonic beam and
analyzed by mass resolved resonant two photon absorption and ionization (R2PI) and by collision induced
mass spectrometry (CID-MS). The absence of the solvent allows to study these systems in the isolated state
free of undesired solvent effects which may level off the differences in their properties. The gas phase results
have been compared to theoretical estimates of the structure and stability of the systems under investigation. |
url |
http://dx.doi.org/10.1155/S1110662X04000030 |
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