Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes

Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes

Manganese-based hydrogenation catalysts are sensitive to high temperatures and may degrade under industrially relevant conditions. Here, the authors report a highly efficient manganese pincer pre-catalyst displaying high TOF values (up to 41 000 h−1) and stability (TON up to 200 000) at loadings as...

Full description

Bibliographic Details
Main Authors: Wenjun Yang, Ivan Yu. Chernyshov, Robin K. A. van Schendel, Manuela Weber, Christian Müller, Georgy A. Filonenko, Evgeny A. Pidko
Format: Article
Language:English
Published: Nature Publishing Group 2021-01-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-20168-2
id doaj-2333ee82b085469698a0e16aa50c9ae0
record_format Article
spelling doaj-2333ee82b085469698a0e16aa50c9ae02021-01-10T12:20:03ZengNature Publishing GroupNature Communications2041-17232021-01-011211810.1038/s41467-020-20168-2Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexesWenjun Yang0Ivan Yu. Chernyshov1Robin K. A. van Schendel2Manuela Weber3Christian Müller4Georgy A. Filonenko5Evgeny A. Pidko6Inorganic Systems Engineering group, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of TechnologyTheoMAT Group, ChemBio cluster, ITMO UniversityInorganic Systems Engineering group, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of TechnologyInstitute of Chemistry and Biochemistry, Freie Universität BerlinInstitute of Chemistry and Biochemistry, Freie Universität BerlinInorganic Systems Engineering group, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of TechnologyInorganic Systems Engineering group, Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of TechnologyManganese-based hydrogenation catalysts are sensitive to high temperatures and may degrade under industrially relevant conditions. Here, the authors report a highly efficient manganese pincer pre-catalyst displaying high TOF values (up to 41 000 h−1) and stability (TON up to 200 000) at loadings as low as 5-200 ppm.https://doi.org/10.1038/s41467-020-20168-2
collection DOAJ
language English
format Article
sources DOAJ
author Wenjun Yang
Ivan Yu. Chernyshov
Robin K. A. van Schendel
Manuela Weber
Christian Müller
Georgy A. Filonenko
Evgeny A. Pidko
spellingShingle Wenjun Yang
Ivan Yu. Chernyshov
Robin K. A. van Schendel
Manuela Weber
Christian Müller
Georgy A. Filonenko
Evgeny A. Pidko
Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
Nature Communications
author_facet Wenjun Yang
Ivan Yu. Chernyshov
Robin K. A. van Schendel
Manuela Weber
Christian Müller
Georgy A. Filonenko
Evgeny A. Pidko
author_sort Wenjun Yang
title Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
title_short Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
title_full Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
title_fullStr Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
title_full_unstemmed Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
title_sort robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor mn(i) pincer complexes
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2021-01-01
description Manganese-based hydrogenation catalysts are sensitive to high temperatures and may degrade under industrially relevant conditions. Here, the authors report a highly efficient manganese pincer pre-catalyst displaying high TOF values (up to 41 000 h−1) and stability (TON up to 200 000) at loadings as low as 5-200 ppm.
url https://doi.org/10.1038/s41467-020-20168-2
work_keys_str_mv AT wenjunyang robustandefficienthydrogenationofcarbonylcompoundscatalysedbymixeddonormnipincercomplexes
AT ivanyuchernyshov robustandefficienthydrogenationofcarbonylcompoundscatalysedbymixeddonormnipincercomplexes
AT robinkavanschendel robustandefficienthydrogenationofcarbonylcompoundscatalysedbymixeddonormnipincercomplexes
AT manuelaweber robustandefficienthydrogenationofcarbonylcompoundscatalysedbymixeddonormnipincercomplexes
AT christianmuller robustandefficienthydrogenationofcarbonylcompoundscatalysedbymixeddonormnipincercomplexes
AT georgyafilonenko robustandefficienthydrogenationofcarbonylcompoundscatalysedbymixeddonormnipincercomplexes
AT evgenyapidko robustandefficienthydrogenationofcarbonylcompoundscatalysedbymixeddonormnipincercomplexes
_version_ 1724342967548772352

Similar Items