Dibromido(2,2′-dimethyl-4,4′-bi-1,3-thiazole-κ2N,N′)mercury(II)
The asymmetric unit of the title compound, [HgBr2(C8H8N2S2)], contains two crystallographically independent molecules. The HgII atoms are four-coordinated in a distorted tetrahedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thiazole ligand and two Br atoms....
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810051494 |
| Summary: | The asymmetric unit of the title compound, [HgBr2(C8H8N2S2)], contains two crystallographically independent molecules. The HgII atoms are four-coordinated in a distorted tetrahedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thiazole ligand and two Br atoms. In the crystal structure, intermolecular C—H...Br hydrogen bonds and π–π contacts between the thiazole rings [centroid–centroid distances = 3.670 (3) and 3.614 (2) Å] stabilize the structure. |
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| ISSN: | 1600-5368 |