Development of Biodegradable Flame-Retardant Bamboo Charcoal Composites, Part II: Thermal Degradation, Gas Phase, and Elemental Analyses

• Main Authors: Shanshan Wang, Liang Zhang, Kate Semple, Min Zhang, Wenbiao Zhang, Chunping Dai
• Format: Article
• Language: English
• Published: MDPI AG 2020-09-01
• Series: Polymers
• Subjects: bamboo charcoal; aluminum hypophosphite; polylactic acid; composites; flame retardancy
• Online Access: https://www.mdpi.com/2073-4360/12/10/2238

Bamboo charcoal (BC) and aluminum hypophosphite (AHP) singly and in combination were investigated as flame-retardant fillers for polylactic acid (PLA). A set of BC/PLA/AHP composites were prepared by melt-blending and tested for thermal and flame-retardancy properties in Part I. Here, in Part II, the results for differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transform infrared (FTIR), thermogravimetry-Fourier transform infrared spectrometry (TG-FTIR), X-ray diffraction (XRD), and X-ray photoelectron analysis (XPS) are presented. The fillers either singly or together promoted earlier initial thermal degradation of the surface of BC/PLA/AHP composites, with a carbon residue rate up to 40.3%, providing a protective layer of char. Additionally, BC promotes heterogeneous nucleation of PLA, while AHP improves the mechanical properties and machinability. Gaseous combustion products CO, aromatic compounds, and carbonyl groups were significantly suppressed in only the BC-PLA composite, but not pure PLA or the BC/PLA/AHP system. The flame-retardant effects of AHP and BC-AHP co-addition combine effective gas-phase and condensed-phase surface phenomena that provide a heat and oxygen barrier, protecting the inner matrix. While it generated much CO₂ and smoke during combustion, it is not yet clear whether BC addition on its own contributes any significant gas phase protection for PLA.