SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NOVEL Mg(II) COMPLEX WITH 1,2-PHENYLENEDIOXYDIACETIC ACID
A novel Mg(II) complex, [Mg(HL)2•(H2O)4]•4H2O•HCl (HL = 1,2-phenylenedioxydiacetato), has been synthesized by the reaction of 1,2-phenylenedioxydiacetic acid, NaOH and MgCl2•6H2O in one-pot. The compound was characterized by X-ray single crystal diffraction analysis. The crystal of the title complex...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2014-11-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| Subjects: | |
| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201403&vol=3&aid=4157 |
| Summary: | A novel Mg(II) complex, [Mg(HL)2•(H2O)4]•4H2O•HCl (HL = 1,2-phenylenedioxydiacetato), has been synthesized by the reaction of 1,2-phenylenedioxydiacetic acid, NaOH and MgCl2•6H2O in one-pot. The compound was characterized by X-ray single crystal diffraction analysis. The crystal of the title complex belongs to monoclinic, space group Pn with a = 10.772(2) Å, b = 9.7145(19) Å, c = 13.996(3) Å, β = 104.32(3)º, V = 1419.1(5) Å3, Z = 2, Dc = 1.498 μg•m-3, μ = 0.245 mm-1, F(000) = 658 and final R1 = 0.0653, ωR2 = 0.1913. The molecules are connected by π-π stacking to form three dimensional network structures. |
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| ISSN: | 1582-540X 1582-540X |