Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives

Acrylic pressure-sensitive adhesives (PSA) based on two monomers: 2-ethylhexyl acrylate and acrylic acid were synthesized in organic solvent ethyl acetate using AIBN (2, 2'-azo-diisobutyronitrile) and new synthesized azo-peresters as radical initiators. After polymerization the visc...

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Format: Article
Language:English
Published: Budapest University of Technology 2008-04-01
Series:eXPRESS Polymer Letters
Subjects:
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0000588&mi=cd
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spelling doaj-21f45b547ebb46ecb077d7779bb30bc92020-11-24T21:26:00ZengBudapest University of Technology eXPRESS Polymer Letters1788-618X2008-04-012427728310.3144/expresspolymlett.2008.33Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesivesAcrylic pressure-sensitive adhesives (PSA) based on two monomers: 2-ethylhexyl acrylate and acrylic acid were synthesized in organic solvent ethyl acetate using AIBN (2, 2'-azo-diisobutyronitrile) and new synthesized azo-peresters as radical initiators. After polymerization the viscosity, molecular weight and polydispersity of synthesized acrylic PSA were evaluated. The novel synthesized radical azo-perester initiators were synthesized, isolated and compared with industrial predominant usable azo-initiator AIBN. http://www.expresspolymlett.com/letolt.php?file=EPL-0000588&mi=cdPolymer synthesis, molecular eAIBNradical azo-perester initiatorsynthesis of acrylic PSAviscosity
collection DOAJ
language English
format Article
sources DOAJ
title Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives
spellingShingle Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives
eXPRESS Polymer Letters
Polymer synthesis, molecular e
AIBN
radical azo-perester initiator
synthesis of acrylic PSA
viscosity
title_short Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives
title_full Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives
title_fullStr Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives
title_full_unstemmed Novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives
title_sort novel azo-peresters radical initiators used for the synthesis of acrylic pressure-sensitive adhesives
publisher Budapest University of Technology
series eXPRESS Polymer Letters
issn 1788-618X
publishDate 2008-04-01
description Acrylic pressure-sensitive adhesives (PSA) based on two monomers: 2-ethylhexyl acrylate and acrylic acid were synthesized in organic solvent ethyl acetate using AIBN (2, 2'-azo-diisobutyronitrile) and new synthesized azo-peresters as radical initiators. After polymerization the viscosity, molecular weight and polydispersity of synthesized acrylic PSA were evaluated. The novel synthesized radical azo-perester initiators were synthesized, isolated and compared with industrial predominant usable azo-initiator AIBN.
topic Polymer synthesis, molecular e
AIBN
radical azo-perester initiator
synthesis of acrylic PSA
viscosity
url http://www.expresspolymlett.com/letolt.php?file=EPL-0000588&mi=cd
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