[1,3-Bis(diphenylphosphino)propane-κ2P,P′]diiodido(perfluoropropyl)rhodium(III) dichloromethane solvate

[1,3-Bis(diphenylphosphino)propane-κ2P,P′]diiodido(perfluoropropyl)rhodium(III) dichloromethane solvate

The structure of the title compound, [RhI2(C3F7)(C27H26P2)]·CH2Cl2, at 110 (2) K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh—C bond is relatively short at 1.996 (6) &...

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Main Authors: Andreas Franken, Stephen L. Gipson, Basu Panthi
Format: Article
Language:English
Published: International Union of Crystallography 2008-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808029978
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spelling doaj-209c066422074bbc8a997656cb0e63ca2020-11-24T21:26:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410m1330m133010.1107/S1600536808029978[1,3-Bis(diphenylphosphino)propane-κ2P,P′]diiodido(perfluoropropyl)rhodium(III) dichloromethane solvateAndreas FrankenStephen L. GipsonBasu PanthiThe structure of the title compound, [RhI2(C3F7)(C27H26P2)]·CH2Cl2, at 110 (2) K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh—C bond is relatively short at 1.996 (6) Å. This short metal–carbon bond length is typical of perfluoro complexes of transition metals and illustrates the enhanced bond strength in these compounds.http://scripts.iucr.org/cgi-bin/paper?S1600536808029978
collection DOAJ
language English
format Article
sources DOAJ
author Andreas Franken
Stephen L. Gipson
Basu Panthi
spellingShingle Andreas Franken
Stephen L. Gipson
Basu Panthi
[1,3-Bis(diphenylphosphino)propane-κ2P,P′]diiodido(perfluoropropyl)rhodium(III) dichloromethane solvate
Acta Crystallographica Section E
author_facet Andreas Franken
Stephen L. Gipson
Basu Panthi
author_sort Andreas Franken
title [1,3-Bis(diphenylphosphino)propane-κ2P,P′]diiodido(perfluoropropyl)rhodium(III) dichloromethane solvate
title_short [1,3-Bis(diphenylphosphino)propane-κ2P,P′]diiodido(perfluoropropyl)rhodium(III) dichloromethane solvate
title_full [1,3-Bis(diphenylphosphino)propane-κ2P,P′]diiodido(perfluoropropyl)rhodium(III) dichloromethane solvate
title_fullStr [1,3-Bis(diphenylphosphino)propane-κ2P,P′]diiodido(perfluoropropyl)rhodium(III) dichloromethane solvate
title_full_unstemmed [1,3-Bis(diphenylphosphino)propane-κ2P,P′]diiodido(perfluoropropyl)rhodium(III) dichloromethane solvate
title_sort [1,3-bis(diphenylphosphino)propane-κ2p,p′]diiodido(perfluoropropyl)rhodium(iii) dichloromethane solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-10-01
description The structure of the title compound, [RhI2(C3F7)(C27H26P2)]·CH2Cl2, at 110 (2) K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh—C bond is relatively short at 1.996 (6) Å. This short metal–carbon bond length is typical of perfluoro complexes of transition metals and illustrates the enhanced bond strength in these compounds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808029978
work_keys_str_mv AT andreasfranken 13bisdiphenylphosphinopropane9542pp8242diiodidoperfluoropropylrhodiumiiidichloromethanesolvate
AT stephenlgipson 13bisdiphenylphosphinopropane9542pp8242diiodidoperfluoropropylrhodiumiiidichloromethanesolvate
AT basupanthi 13bisdiphenylphosphinopropane9542pp8242diiodidoperfluoropropylrhodiumiiidichloromethanesolvate
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