12α-Hydroxy-3,27-dioxooleanano-28,13-lactone

12α-Hydroxy-3,27-dioxooleanano-28,13-lactone

There are two independent molecules in the asymmetric unit of the title compound, C30H44O5. They comprise a triterpenoid skeleton of five six-membered rings and a five-membered lactone ring. The five six-membered rings are all trans-fused. In both independent molecules the D rings adopt a slightly d...

Full description

Bibliographic Details
Main Authors: Jun-yi Hu, Gang-gang Wu, Ying-qian Xu, Guo-yong Xiao, Peng Lei
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812017783
id doaj-2087a8b8e2454e8d8e21739ddce30406
record_format Article
spelling doaj-2087a8b8e2454e8d8e21739ddce304062020-11-25T01:35:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686o1586o158610.1107/S160053681201778312α-Hydroxy-3,27-dioxooleanano-28,13-lactoneJun-yi HuGang-gang WuYing-qian XuGuo-yong XiaoPeng LeiThere are two independent molecules in the asymmetric unit of the title compound, C30H44O5. They comprise a triterpenoid skeleton of five six-membered rings and a five-membered lactone ring. The five six-membered rings are all trans-fused. In both independent molecules the D rings adopt a slightly distorted half-chair conformation due the presence of the lactone ring while the other four six-membered rings all adopt chair conformations. The characteristic carbon–carbon double bond of the oleanoic skeleton is absent. Intermolecular O—H...O hydrogen bonds between the hydroxy and carbonyl groups occur in the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536812017783
collection DOAJ
language English
format Article
sources DOAJ
author Jun-yi Hu
Gang-gang Wu
Ying-qian Xu
Guo-yong Xiao
Peng Lei
spellingShingle Jun-yi Hu
Gang-gang Wu
Ying-qian Xu
Guo-yong Xiao
Peng Lei
12α-Hydroxy-3,27-dioxooleanano-28,13-lactone
Acta Crystallographica Section E
author_facet Jun-yi Hu
Gang-gang Wu
Ying-qian Xu
Guo-yong Xiao
Peng Lei
author_sort Jun-yi Hu
title 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone
title_short 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone
title_full 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone
title_fullStr 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone
title_full_unstemmed 12α-Hydroxy-3,27-dioxooleanano-28,13-lactone
title_sort 12α-hydroxy-3,27-dioxooleanano-28,13-lactone
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description There are two independent molecules in the asymmetric unit of the title compound, C30H44O5. They comprise a triterpenoid skeleton of five six-membered rings and a five-membered lactone ring. The five six-membered rings are all trans-fused. In both independent molecules the D rings adopt a slightly distorted half-chair conformation due the presence of the lactone ring while the other four six-membered rings all adopt chair conformations. The characteristic carbon–carbon double bond of the oleanoic skeleton is absent. Intermolecular O—H...O hydrogen bonds between the hydroxy and carbonyl groups occur in the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812017783
work_keys_str_mv AT junyihu 12amp945hydroxy327dioxooleanano2813lactone
AT ganggangwu 12amp945hydroxy327dioxooleanano2813lactone
AT yingqianxu 12amp945hydroxy327dioxooleanano2813lactone
AT guoyongxiao 12amp945hydroxy327dioxooleanano2813lactone
AT penglei 12amp945hydroxy327dioxooleanano2813lactone
_version_ 1725065766777126912

Similar Items