New Interpretation of X-ray Diffraction Pattern of Vitreous Silica

• Main Author: Shangcong Cheng
• Format: Article
• Language: English
• Published: MDPI AG 2021-03-01
• Series: Ceramics
• Subjects: diffraction pattern; silica glass; cristobalite; continuous random network theory; medium-range structure; nanoflake
• Online Access: https://www.mdpi.com/2571-6131/4/1/8

The striking feature of X-ray diffraction pattern of vitreous silica is that the center of its intense but broad ring is located at nearly the same position as the strongest diffraction ring of β-cristobalite. Two fundamentally different explanations to the diffraction patterns were appeared about 90 years ago, one based on the smallest crystals of β-cristobalite and the other based on the non-crystalline continuous random network. This work briefly outlines the facts supporting and objecting these two hypotheses, and aims to present a new interpretation based on a medium-range ordering structure on the facets of clusters formed in the glass transition process. It will be shown that the new interpretation provides a more satisfactory explanation of the diffraction pattern and physical properties of silica glass, and offers considerable valuable information regarding the nature of glass and glass transition.