Poly[tetramethylammonium [tri-μ2-formato-κ6O:O′-manganate(II)]]
In the title compound, {(C4H12N)[Mn(HCO2)3]}n, the MnII atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination sphere. A three-d...
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International Union of Crystallography
2013-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813024045 |
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doaj-201ad9c48aeb49e9a958dc981af29e392020-11-25T01:35:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-10-016910m541m54110.1107/S1600536813024045Poly[tetramethylammonium [tri-μ2-formato-κ6O:O′-manganate(II)]]Cai-Yun HanMin-Min LiuQin-Qin DangIn the title compound, {(C4H12N)[Mn(HCO2)3]}n, the MnII atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination sphere. A three-dimensional NaCl-type framework is generated in which the tetramethylammonium cations, which lie across mirror planes and occupy the cavities in the polymer structure, form weak C—H...O hydrogen bonds with the formate ligands.http://scripts.iucr.org/cgi-bin/paper?S1600536813024045 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Cai-Yun Han Min-Min Liu Qin-Qin Dang |
| spellingShingle |
Cai-Yun Han Min-Min Liu Qin-Qin Dang Poly[tetramethylammonium [tri-μ2-formato-κ6O:O′-manganate(II)]] Acta Crystallographica Section E |
| author_facet |
Cai-Yun Han Min-Min Liu Qin-Qin Dang |
| author_sort |
Cai-Yun Han |
| title |
Poly[tetramethylammonium [tri-μ2-formato-κ6O:O′-manganate(II)]] |
| title_short |
Poly[tetramethylammonium [tri-μ2-formato-κ6O:O′-manganate(II)]] |
| title_full |
Poly[tetramethylammonium [tri-μ2-formato-κ6O:O′-manganate(II)]] |
| title_fullStr |
Poly[tetramethylammonium [tri-μ2-formato-κ6O:O′-manganate(II)]] |
| title_full_unstemmed |
Poly[tetramethylammonium [tri-μ2-formato-κ6O:O′-manganate(II)]] |
| title_sort |
poly[tetramethylammonium [tri-μ2-formato-κ6o:o′-manganate(ii)]] |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2013-10-01 |
| description |
In the title compound, {(C4H12N)[Mn(HCO2)3]}n, the MnII atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination sphere. A three-dimensional NaCl-type framework is generated in which the tetramethylammonium cations, which lie across mirror planes and occupy the cavities in the polymer structure, form weak C—H...O hydrogen bonds with the formate ligands. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536813024045 |
| work_keys_str_mv |
AT caiyunhan polytetramethylammoniumtri9562formato9546oo8242manganateii AT minminliu polytetramethylammoniumtri9562formato9546oo8242manganateii AT qinqindang polytetramethylammoniumtri9562formato9546oo8242manganateii |
| _version_ |
1725065417620193280 |