Chlorido[N,N′-dibenzyl-N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]copper(II) perchlorate methanol monosolvate

Chlorido[N,N′-dibenzyl-N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]copper(II) perchlorate methanol monosolvate

In the title solvated molecular salt, [CuCl(C28H30N4)]ClO4·CH3OH, the Cu2+ ion is coordinated by the N,N′,N′′,N′′′-tetradentate ligand and a chloride ion, generating a very distorted square-based pyramid...

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Main Authors: Zhi-Quan Pan, Ming Liu, Jia-Wei Mao, Hui-Ting Song
Format: Article
Language:English
Published: International Union of Crystallography 2012-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812017941
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spelling doaj-1fcc4c29891443d893161bed1aa086892020-11-25T00:51:25ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-05-01685m694m69510.1107/S1600536812017941Chlorido[N,N′-dibenzyl-N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]copper(II) perchlorate methanol monosolvateZhi-Quan PanMing LiuJia-Wei MaoHui-Ting SongIn the title solvated molecular salt, [CuCl(C28H30N4)]ClO4·CH3OH, the Cu2+ ion is coordinated by the N,N′,N′′,N′′′-tetradentate ligand and a chloride ion, generating a very distorted square-based pyramidal CuN4Cl coordination geometry with the Cl− ion in the basal position. In the crystal, the solvent molecules and anions are linked by weak O—H...O hydrogen bonding.http://scripts.iucr.org/cgi-bin/paper?S1600536812017941
collection DOAJ
language English
format Article
sources DOAJ
author Zhi-Quan Pan
Ming Liu
Jia-Wei Mao
Hui-Ting Song
spellingShingle Zhi-Quan Pan
Ming Liu
Jia-Wei Mao
Hui-Ting Song
Chlorido[N,N′-dibenzyl-N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]copper(II) perchlorate methanol monosolvate
Acta Crystallographica Section E
author_facet Zhi-Quan Pan
Ming Liu
Jia-Wei Mao
Hui-Ting Song
author_sort Zhi-Quan Pan
title Chlorido[N,N′-dibenzyl-N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]copper(II) perchlorate methanol monosolvate
title_short Chlorido[N,N′-dibenzyl-N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]copper(II) perchlorate methanol monosolvate
title_full Chlorido[N,N′-dibenzyl-N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]copper(II) perchlorate methanol monosolvate
title_fullStr Chlorido[N,N′-dibenzyl-N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]copper(II) perchlorate methanol monosolvate
title_full_unstemmed Chlorido[N,N′-dibenzyl-N,N′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]copper(II) perchlorate methanol monosolvate
title_sort chlorido[n,n′-dibenzyl-n,n′-bis(pyridin-2-ylmethyl)ethane-1,2-diamine]copper(ii) perchlorate methanol monosolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-05-01
description In the title solvated molecular salt, [CuCl(C28H30N4)]ClO4·CH3OH, the Cu2+ ion is coordinated by the N,N′,N′′,N′′′-tetradentate ligand and a chloride ion, generating a very distorted square-based pyramidal CuN4Cl coordination geometry with the Cl− ion in the basal position. In the crystal, the solvent molecules and anions are linked by weak O—H...O hydrogen bonding.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812017941
work_keys_str_mv AT zhiquanpan chloridonnamp8242dibenzylnnamp8242bispyridin2ylmethylethane12diaminecopperiiperchloratemethanolmonosolvate
AT mingliu chloridonnamp8242dibenzylnnamp8242bispyridin2ylmethylethane12diaminecopperiiperchloratemethanolmonosolvate
AT jiaweimao chloridonnamp8242dibenzylnnamp8242bispyridin2ylmethylethane12diaminecopperiiperchloratemethanolmonosolvate
AT huitingsong chloridonnamp8242dibenzylnnamp8242bispyridin2ylmethylethane12diaminecopperiiperchloratemethanolmonosolvate
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