2,2′-Diazinodimethylidyne)di-o-phenylene) dibenzoate

2,2′-Diazinodimethylidyne)di-o-phenylene) dibenzoate

The title compound, C28H20N2O4, was synthesized by the reaction of 2-(hydrazonomethyl)phenyl benzoate with iodine. The molecule possesses a crystallographically imposed center of symmetry at the mid-point of the hydrazine N—N bond. The substituents at the ends of the C=N bonds adopt an E,E...

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Main Authors: Monika Mukherjee, Madeleine Helliwell, Somnath Ghosh, Sharmila Basu, Basab Chattopadhyay
Format: Article
Language:English
Published: International Union of Crystallography 2008-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808010155
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spelling doaj-1fc4acef473242e09e4cd779aa7ddd2e2020-11-25T01:14:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645o866o86610.1107/S16005368080101552,2′-Diazinodimethylidyne)di-o-phenylene) dibenzoateMonika MukherjeeMadeleine HelliwellSomnath GhoshSharmila BasuBasab ChattopadhyayThe title compound, C28H20N2O4, was synthesized by the reaction of 2-(hydrazonomethyl)phenyl benzoate with iodine. The molecule possesses a crystallographically imposed center of symmetry at the mid-point of the hydrazine N—N bond. The substituents at the ends of the C=N bonds adopt an E,E configuration. Intermolecular C—H...π(arene) hydrogen bonds and aromatic π–π stacking interactions [centroid–centroid distance 3.900 (1) Å] link the molecules into (100) sheets. In addition, there is an intermolecular C—H...O hydrogen-bond interaction.http://scripts.iucr.org/cgi-bin/paper?S1600536808010155
collection DOAJ
language English
format Article
sources DOAJ
author Monika Mukherjee
Madeleine Helliwell
Somnath Ghosh
Sharmila Basu
Basab Chattopadhyay
spellingShingle Monika Mukherjee
Madeleine Helliwell
Somnath Ghosh
Sharmila Basu
Basab Chattopadhyay
2,2′-Diazinodimethylidyne)di-o-phenylene) dibenzoate
Acta Crystallographica Section E
author_facet Monika Mukherjee
Madeleine Helliwell
Somnath Ghosh
Sharmila Basu
Basab Chattopadhyay
author_sort Monika Mukherjee
title 2,2′-Diazinodimethylidyne)di-o-phenylene) dibenzoate
title_short 2,2′-Diazinodimethylidyne)di-o-phenylene) dibenzoate
title_full 2,2′-Diazinodimethylidyne)di-o-phenylene) dibenzoate
title_fullStr 2,2′-Diazinodimethylidyne)di-o-phenylene) dibenzoate
title_full_unstemmed 2,2′-Diazinodimethylidyne)di-o-phenylene) dibenzoate
title_sort 2,2′-diazinodimethylidyne)di-o-phenylene) dibenzoate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-05-01
description The title compound, C28H20N2O4, was synthesized by the reaction of 2-(hydrazonomethyl)phenyl benzoate with iodine. The molecule possesses a crystallographically imposed center of symmetry at the mid-point of the hydrazine N—N bond. The substituents at the ends of the C=N bonds adopt an E,E configuration. Intermolecular C—H...π(arene) hydrogen bonds and aromatic π–π stacking interactions [centroid–centroid distance 3.900 (1) Å] link the molecules into (100) sheets. In addition, there is an intermolecular C—H...O hydrogen-bond interaction.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808010155
work_keys_str_mv AT monikamukherjee 228242diazinodimethylidynediophenylenedibenzoate
AT madeleinehelliwell 228242diazinodimethylidynediophenylenedibenzoate
AT somnathghosh 228242diazinodimethylidynediophenylenedibenzoate
AT sharmilabasu 228242diazinodimethylidynediophenylenedibenzoate
AT basabchattopadhyay 228242diazinodimethylidynediophenylenedibenzoate
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