(2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV)
The Sn atom in the title compound, [Sn(C7H7)2(C5H5N2O)Cl], shows a distorted C2ClNOSn trigonal-bipyramidal coordination, with a Cl–Sn–O axial angle of 163.77 (3)°, but the C—Sn—C angle [141.43 (7)&am...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809020339 |
| Summary: | The Sn atom in the title compound, [Sn(C7H7)2(C5H5N2O)Cl], shows a distorted C2ClNOSn trigonal-bipyramidal coordination, with a Cl–Sn–O axial angle of 163.77 (3)°, but the C—Sn—C angle [141.43 (7)°] deviates from 120°. The chelating ligand exists in a zwitterionic form. Adjacent molecules are linked by an N—Hpyridinium...O hydrogen bond, forming a chain running along the c axis of the orthorhombic unit cell. |
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| ISSN: | 1600-5368 |