Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3

Bimetallic di- and triorganotin(IV) germanium carboxylates were synthesized and characterized by elemental analyses, as well as IR, multinuclear NMR (1H, 13C, 119Sn) spectroscopy and tested for bioactivity. The structure of the representative compound, [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3, was determined...

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Main Authors: Khosa-Kaleem Muhammad, Mazhar Muhammad, Ali Saqib, Dastgir Sarim, Parvez Masood, Malik Abdul
Format: Article
Language:English
Published: Serbian Chemical Society 2006-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390610001K.pdf
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spelling doaj-1e73e37da74d44a79ff69b7f16f514542020-12-24T14:31:03ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51391820-74212006-01-0171101001101310.2298/JSC0610001K0352-51390610001KSynthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3Khosa-Kaleem Muhammad0Mazhar Muhammad1Ali Saqib2Dastgir Sarim3Parvez Masood4Malik Abdul5Department of Chemistry, Quaid-i-Azam University, IslamabadDepartment of Chemistry, Quaid-i-Azam University, IslamabadDepartment of Chemistry, Quaid-i-Azam University, IslamabadDepartment of Chemistry, Quaid-i-Azam University, IslamabadDepartment of Chemistry, University of Calgary, University Drive NW, Calgary, AlbertaHEJ Research Institute of Chemistry, International Centre for Chemical Sciences, University of Karachi, KarachiBimetallic di- and triorganotin(IV) germanium carboxylates were synthesized and characterized by elemental analyses, as well as IR, multinuclear NMR (1H, 13C, 119Sn) spectroscopy and tested for bioactivity. The structure of the representative compound, [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3, was determined by X-ray analysis and found to have a distorted trigonal bipyramidal geometry around the tin atom. Some selected compounds were also screened against different microbes and showed promising antibacterial and antifungal activity. .http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390610001K.pdforganotin(iv) carboxylatesorganogermaniumspectroscopybioactivityx-ray structure
collection DOAJ
language English
format Article
sources DOAJ
author Khosa-Kaleem Muhammad
Mazhar Muhammad
Ali Saqib
Dastgir Sarim
Parvez Masood
Malik Abdul
spellingShingle Khosa-Kaleem Muhammad
Mazhar Muhammad
Ali Saqib
Dastgir Sarim
Parvez Masood
Malik Abdul
Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3
Journal of the Serbian Chemical Society
organotin(iv) carboxylates
organogermanium
spectroscopy
bioactivity
x-ray structure
author_facet Khosa-Kaleem Muhammad
Mazhar Muhammad
Ali Saqib
Dastgir Sarim
Parvez Masood
Malik Abdul
author_sort Khosa-Kaleem Muhammad
title Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3
title_short Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3
title_full Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3
title_fullStr Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3
title_full_unstemmed Synthesis, spectroscopic and biological investigations of di-and triorganotin(IV) derivatives containing germanium: X-ray study of [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3
title_sort synthesis, spectroscopic and biological investigations of di-and triorganotin(iv) derivatives containing germanium: x-ray study of [ph3gech(n-c3h7)ch2co2]sn[ch3]3
publisher Serbian Chemical Society
series Journal of the Serbian Chemical Society
issn 0352-5139
1820-7421
publishDate 2006-01-01
description Bimetallic di- and triorganotin(IV) germanium carboxylates were synthesized and characterized by elemental analyses, as well as IR, multinuclear NMR (1H, 13C, 119Sn) spectroscopy and tested for bioactivity. The structure of the representative compound, [Ph3GeCH(n-C3H7)CH2CO2]Sn[CH3]3, was determined by X-ray analysis and found to have a distorted trigonal bipyramidal geometry around the tin atom. Some selected compounds were also screened against different microbes and showed promising antibacterial and antifungal activity. .
topic organotin(iv) carboxylates
organogermanium
spectroscopy
bioactivity
x-ray structure
url http://www.doiserbia.nb.rs/img/doi/0352-5139/2006/0352-51390610001K.pdf
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