Ru-catalyzed dehydrogenative coupling of carboxylic acids and silanes - a new method for the preparation of silyl ester
Ru3(CO)12/EtI has been found to be an efficient catalyst system for the dehydrosilylation of carboxylic acids with silanes. In the presence of 1 mol% Ru3(CO)12 and 4 mol% EtI, dehydrosilylation reactions in toluene afforded the corresponding silyl esters at 100 °C in good and high yields.
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Beilstein-Institut
2008-07-01
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| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.4.27 |