Catalytic test-method for determination of ruthenium microquantities based on methyl orange oxidation with potassium periodate

A catalytic test-method for the determination of ruthenium based on methyl orange oxidation by potassium periodate at pH =1 on a paper carrier was proposed. The conditions for the indicator reaction performance were optimized. It is possible to determine ruthenium in the range of its concentrations...

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Main Authors: E. G. Khomutova, N. A. Maltseva, S. A. Zagorodnikova
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2012-08-01
Series:Тонкие химические технологии
Subjects:
Online Access:https://www.finechem-mirea.ru/jour/article/view/721
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spelling doaj-1db08d8361da472f87e1dbf0f5fba3b92021-07-28T13:23:56ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752012-08-01748183715Catalytic test-method for determination of ruthenium microquantities based on methyl orange oxidation with potassium periodateE. G. Khomutova0N. A. Maltseva1S. A. Zagorodnikova2M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571ОАО «НПК «Суперметалл»A catalytic test-method for the determination of ruthenium based on methyl orange oxidation by potassium periodate at pH =1 on a paper carrier was proposed. The conditions for the indicator reaction performance were optimized. It is possible to determine ruthenium in the range of its concentrations 0.010 ÷ 0.55 µg/ml .The detection limit equals to 0.0035 µg/ml, the relative standard deviation (RSD) is not higher than 0.058. The accuracy of the analysis results was confirmed by the traditional added - found method.https://www.finechem-mirea.ru/jour/article/view/721test-methodcatalytic indicator reactionruthenium detection
collection DOAJ
language Russian
format Article
sources DOAJ
author E. G. Khomutova
N. A. Maltseva
S. A. Zagorodnikova
spellingShingle E. G. Khomutova
N. A. Maltseva
S. A. Zagorodnikova
Catalytic test-method for determination of ruthenium microquantities based on methyl orange oxidation with potassium periodate
Тонкие химические технологии
test-method
catalytic indicator reaction
ruthenium detection
author_facet E. G. Khomutova
N. A. Maltseva
S. A. Zagorodnikova
author_sort E. G. Khomutova
title Catalytic test-method for determination of ruthenium microquantities based on methyl orange oxidation with potassium periodate
title_short Catalytic test-method for determination of ruthenium microquantities based on methyl orange oxidation with potassium periodate
title_full Catalytic test-method for determination of ruthenium microquantities based on methyl orange oxidation with potassium periodate
title_fullStr Catalytic test-method for determination of ruthenium microquantities based on methyl orange oxidation with potassium periodate
title_full_unstemmed Catalytic test-method for determination of ruthenium microquantities based on methyl orange oxidation with potassium periodate
title_sort catalytic test-method for determination of ruthenium microquantities based on methyl orange oxidation with potassium periodate
publisher MIREA - Russian Technological University
series Тонкие химические технологии
issn 2410-6593
2686-7575
publishDate 2012-08-01
description A catalytic test-method for the determination of ruthenium based on methyl orange oxidation by potassium periodate at pH =1 on a paper carrier was proposed. The conditions for the indicator reaction performance were optimized. It is possible to determine ruthenium in the range of its concentrations 0.010 ÷ 0.55 µg/ml .The detection limit equals to 0.0035 µg/ml, the relative standard deviation (RSD) is not higher than 0.058. The accuracy of the analysis results was confirmed by the traditional added - found method.
topic test-method
catalytic indicator reaction
ruthenium detection
url https://www.finechem-mirea.ru/jour/article/view/721
work_keys_str_mv AT egkhomutova catalytictestmethodfordeterminationofrutheniummicroquantitiesbasedonmethylorangeoxidationwithpotassiumperiodate
AT namaltseva catalytictestmethodfordeterminationofrutheniummicroquantitiesbasedonmethylorangeoxidationwithpotassiumperiodate
AT sazagorodnikova catalytictestmethodfordeterminationofrutheniummicroquantitiesbasedonmethylorangeoxidationwithpotassiumperiodate
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