Ionic conductivity and vibration spectra of complex phosphates in the Li3PO4–Na3PO4–InPO4
Some properties of lithium-indium complex phosphates in the previously investigated Li3PO4-Na3PO4-InPO4 ternary system were studied. Ionic conductivity of isolated phases at 300ºC was measured. Vibration spectra of the investigated compounds were registered for 6Li → 7Li substituted samples from 140...
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MIREA - Russian Technological University
2011-06-01
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| Series: | Тонкие химические технологии |
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| Online Access: | https://www.finechem-mirea.ru/jour/article/view/843 |
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doaj-1d5921e4b4ff4f88ae8306a39ac6a1c32021-07-28T13:23:54ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752011-06-01638286837Ionic conductivity and vibration spectra of complex phosphates in the Li3PO4–Na3PO4–InPO4A. M. Potapova0G. V. Zimina1V. V. Fomichev2M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571Some properties of lithium-indium complex phosphates in the previously investigated Li3PO4-Na3PO4-InPO4 ternary system were studied. Ionic conductivity of isolated phases at 300ºC was measured. Vibration spectra of the investigated compounds were registered for 6Li → 7Li substituted samples from 1400 to 200 cm-1 frequency range. Isotope shifts under 6Li → 7Li substitution were observed for all the complex phosphates. The obtained results allowed to reveal intrinsic lithium sublattice vibration and to relate complex phosphates structure to ionic conductivity magnitude.https://www.finechem-mirea.ru/jour/article/view/843complex phosphatesionic conductivityimpedance spectroscopyraman light scatteringinfrared (ir) analysis |
| collection |
DOAJ |
| language |
Russian |
| format |
Article |
| sources |
DOAJ |
| author |
A. M. Potapova G. V. Zimina V. V. Fomichev |
| spellingShingle |
A. M. Potapova G. V. Zimina V. V. Fomichev Ionic conductivity and vibration spectra of complex phosphates in the Li3PO4–Na3PO4–InPO4 Тонкие химические технологии complex phosphates ionic conductivity impedance spectroscopy raman light scattering infrared (ir) analysis |
| author_facet |
A. M. Potapova G. V. Zimina V. V. Fomichev |
| author_sort |
A. M. Potapova |
| title |
Ionic conductivity and vibration spectra of complex phosphates in the Li3PO4–Na3PO4–InPO4 |
| title_short |
Ionic conductivity and vibration spectra of complex phosphates in the Li3PO4–Na3PO4–InPO4 |
| title_full |
Ionic conductivity and vibration spectra of complex phosphates in the Li3PO4–Na3PO4–InPO4 |
| title_fullStr |
Ionic conductivity and vibration spectra of complex phosphates in the Li3PO4–Na3PO4–InPO4 |
| title_full_unstemmed |
Ionic conductivity and vibration spectra of complex phosphates in the Li3PO4–Na3PO4–InPO4 |
| title_sort |
ionic conductivity and vibration spectra of complex phosphates in the li3po4–na3po4–inpo4 |
| publisher |
MIREA - Russian Technological University |
| series |
Тонкие химические технологии |
| issn |
2410-6593 2686-7575 |
| publishDate |
2011-06-01 |
| description |
Some properties of lithium-indium complex phosphates in the previously investigated Li3PO4-Na3PO4-InPO4 ternary system were studied. Ionic conductivity of isolated phases at 300ºC was measured. Vibration spectra of the investigated compounds were registered for 6Li → 7Li substituted samples from 1400 to 200 cm-1 frequency range. Isotope shifts under 6Li → 7Li substitution were observed for all the complex phosphates. The obtained results allowed to reveal intrinsic lithium sublattice vibration and to relate complex phosphates structure to ionic conductivity magnitude. |
| topic |
complex phosphates ionic conductivity impedance spectroscopy raman light scattering infrared (ir) analysis |
| url |
https://www.finechem-mirea.ru/jour/article/view/843 |
| work_keys_str_mv |
AT ampotapova ionicconductivityandvibrationspectraofcomplexphosphatesintheli3po4na3po4inpo4 AT gvzimina ionicconductivityandvibrationspectraofcomplexphosphatesintheli3po4na3po4inpo4 AT vvfomichev ionicconductivityandvibrationspectraofcomplexphosphatesintheli3po4na3po4inpo4 |
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1721275153479892992 |