Di-μ-hydroxido-κ4O:O-μ-trifluoromethanesulfonato-κ2O:O′-bis[(5,5′-dimethyl-2,2-bipyridine-κ2N,N′)(η5-pentamethylcyclopentadienyl)ytterbium(III)] tetraphenylborate 5,5′-dimethyl-2,2-bipyridine

Di-μ-hydroxido-κ4O:O-μ-trifluoromethanesulfonato-κ2O:O′-bis[(5,5′-dimethyl-2,2-bipyridine-κ2N,N′)(η5-pentamethylcyclopentadienyl)ytterbium(III)] tetraphenylborate 5,5′-dimethyl-2,2-bipyridine

The title compound, [Yb2(CF3O3S)(C10H15)2(OH)2(C12H12N2)2](C24H20B)·C12H12N2, crystallizes as a half-sandwich complex with a bridging trifluoromethanesulfonate as well as two bridging hydroxide groups. The bound bipyridine ligands have N—C—C—N torsion angles of...

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Main Author: Daniel Kazhdan
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808002791
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spelling doaj-1ce127eb7499442f828cc3e5b91cfd5d2020-11-25T01:11:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m435m43510.1107/S1600536808002791Di-μ-hydroxido-κ4O:O-μ-trifluoromethanesulfonato-κ2O:O′-bis[(5,5′-dimethyl-2,2-bipyridine-κ2N,N′)(η5-pentamethylcyclopentadienyl)ytterbium(III)] tetraphenylborate 5,5′-dimethyl-2,2-bipyridineDaniel KazhdanThe title compound, [Yb2(CF3O3S)(C10H15)2(OH)2(C12H12N2)2](C24H20B)·C12H12N2, crystallizes as a half-sandwich complex with a bridging trifluoromethanesulfonate as well as two bridging hydroxide groups. The bound bipyridine ligands have N—C—C—N torsion angles of 13.1 (9) and −12.1 (8)°. The structure also contains an uncoordinated 5,5′-dimethyl-2,2′-bipyridine molecule with an N—C—C—N torsion angle of 169.5 (7)°. The triply bridged Yb centers are 3.5990 (4) Å apart. The Yb—N bond lengths are in the range 2.389 (6)–2.424 (5) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536808002791
collection DOAJ
language English
format Article
sources DOAJ
author Daniel Kazhdan
spellingShingle Daniel Kazhdan
Di-μ-hydroxido-κ4O:O-μ-trifluoromethanesulfonato-κ2O:O′-bis[(5,5′-dimethyl-2,2-bipyridine-κ2N,N′)(η5-pentamethylcyclopentadienyl)ytterbium(III)] tetraphenylborate 5,5′-dimethyl-2,2-bipyridine
Acta Crystallographica Section E
author_facet Daniel Kazhdan
author_sort Daniel Kazhdan
title Di-μ-hydroxido-κ4O:O-μ-trifluoromethanesulfonato-κ2O:O′-bis[(5,5′-dimethyl-2,2-bipyridine-κ2N,N′)(η5-pentamethylcyclopentadienyl)ytterbium(III)] tetraphenylborate 5,5′-dimethyl-2,2-bipyridine
title_short Di-μ-hydroxido-κ4O:O-μ-trifluoromethanesulfonato-κ2O:O′-bis[(5,5′-dimethyl-2,2-bipyridine-κ2N,N′)(η5-pentamethylcyclopentadienyl)ytterbium(III)] tetraphenylborate 5,5′-dimethyl-2,2-bipyridine
title_full Di-μ-hydroxido-κ4O:O-μ-trifluoromethanesulfonato-κ2O:O′-bis[(5,5′-dimethyl-2,2-bipyridine-κ2N,N′)(η5-pentamethylcyclopentadienyl)ytterbium(III)] tetraphenylborate 5,5′-dimethyl-2,2-bipyridine
title_fullStr Di-μ-hydroxido-κ4O:O-μ-trifluoromethanesulfonato-κ2O:O′-bis[(5,5′-dimethyl-2,2-bipyridine-κ2N,N′)(η5-pentamethylcyclopentadienyl)ytterbium(III)] tetraphenylborate 5,5′-dimethyl-2,2-bipyridine
title_full_unstemmed Di-μ-hydroxido-κ4O:O-μ-trifluoromethanesulfonato-κ2O:O′-bis[(5,5′-dimethyl-2,2-bipyridine-κ2N,N′)(η5-pentamethylcyclopentadienyl)ytterbium(III)] tetraphenylborate 5,5′-dimethyl-2,2-bipyridine
title_sort di-μ-hydroxido-κ4o:o-μ-trifluoromethanesulfonato-κ2o:o′-bis[(5,5′-dimethyl-2,2-bipyridine-κ2n,n′)(η5-pentamethylcyclopentadienyl)ytterbium(iii)] tetraphenylborate 5,5′-dimethyl-2,2-bipyridine
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-02-01
description The title compound, [Yb2(CF3O3S)(C10H15)2(OH)2(C12H12N2)2](C24H20B)·C12H12N2, crystallizes as a half-sandwich complex with a bridging trifluoromethanesulfonate as well as two bridging hydroxide groups. The bound bipyridine ligands have N—C—C—N torsion angles of 13.1 (9) and −12.1 (8)°. The structure also contains an uncoordinated 5,5′-dimethyl-2,2′-bipyridine molecule with an N—C—C—N torsion angle of 169.5 (7)°. The triply bridged Yb centers are 3.5990 (4) Å apart. The Yb—N bond lengths are in the range 2.389 (6)–2.424 (5) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808002791
work_keys_str_mv AT danielkazhdan di956hydroxido9544oo956trifluoromethanesulfonato9542oo8242bis558242dimethyl22bipyridine9542nn82429515pentamethylcyclopentadienylytterbiumiiitetraphenylborate558242dimethyl22bipyridine
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