Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water

A novel heterogeneous transition-metal catalyst comprising a polymer-supported terpyridine palladium(II) complex was prepared and found to promote the Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost, reactions in water under aerobic conditions with a high to excellent yield. The catalyst...

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Bibliographic Details
Main Authors: Takuya Nagamine, Kosuke Kimura, Toshimasa Suzuka
Format: Article
Language:English
Published: MDPI AG 2011-03-01
Series:Polymers
Subjects:
Online Access:http://www.mdpi.com/2073-4360/3/1/621/
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spelling doaj-1cc8278481c44054897cee46594305612020-11-24T22:06:30ZengMDPI AGPolymers2073-43602011-03-013162163910.3390/polym3010621Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in WaterTakuya NagamineKosuke KimuraToshimasa SuzukaA novel heterogeneous transition-metal catalyst comprising a polymer-supported terpyridine palladium(II) complex was prepared and found to promote the Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost, reactions in water under aerobic conditions with a high to excellent yield. The catalyst was recovered by simple filtration and directly reused several times without loss of catalytic activity. http://www.mdpi.com/2073-4360/3/1/621/palladiumterpyridinecross-couplingpolymer-supported synthesis
collection DOAJ
language English
format Article
sources DOAJ
author Takuya Nagamine
Kosuke Kimura
Toshimasa Suzuka
spellingShingle Takuya Nagamine
Kosuke Kimura
Toshimasa Suzuka
Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water
Polymers
palladium
terpyridine
cross-coupling
polymer-supported synthesis
author_facet Takuya Nagamine
Kosuke Kimura
Toshimasa Suzuka
author_sort Takuya Nagamine
title Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water
title_short Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water
title_full Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water
title_fullStr Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water
title_full_unstemmed Reusable Polymer-Supported Terpyridine Palladium Complex for Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost Reaction in Water
title_sort reusable polymer-supported terpyridine palladium complex for suzuki-miyaura, mizoroki-heck, sonogashira, and tsuji-trost reaction in water
publisher MDPI AG
series Polymers
issn 2073-4360
publishDate 2011-03-01
description A novel heterogeneous transition-metal catalyst comprising a polymer-supported terpyridine palladium(II) complex was prepared and found to promote the Suzuki-Miyaura, Mizoroki-Heck, Sonogashira, and Tsuji-Trost, reactions in water under aerobic conditions with a high to excellent yield. The catalyst was recovered by simple filtration and directly reused several times without loss of catalytic activity.
topic palladium
terpyridine
cross-coupling
polymer-supported synthesis
url http://www.mdpi.com/2073-4360/3/1/621/
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