cis-Dichlorido(6,11-dihydrodibenzo[b,f][1,4]dithiocine-κ2S,S′)palladium(II)
In the title compound, [PdCl2(C14H12S2)], the PdII atom features a square-planar coordination to the two S atoms of the dithiocine ligand and two Cl− ions. The dithiocine ligand forms a pair of metallacycle rings, with seven (C4S2Pd) and five (C2S2Pd) members, respectively. The benzylic part of the...
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International Union of Crystallography
2016-06-01
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431461600852X |
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doaj-1cbc384da71546bfa1f2c526e3d1f1092020-11-24T21:56:00ZengInternational Union of CrystallographyIUCrData2414-31462016-06-0116x16085210.1107/S241431461600852Xsj4043cis-Dichlorido(6,11-dihydrodibenzo[b,f][1,4]dithiocine-κ2S,S′)palladium(II)Sylvain Bernès0Jorge Tiburcio1Hugo Torrens2Instituto de Física, Universidad Autónoma de Puebla, Av. San Claudio y 18 Sur, 72570 Puebla, Pue., MexicoDepartamento de Química, CINVESTAV, Av. Instituto Politécnico Nacional 2508, San Pedro Zacatenco, 07360 México D.F., MexicoFacultad de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, 04510 México D.F., MexicoIn the title compound, [PdCl2(C14H12S2)], the PdII atom features a square-planar coordination to the two S atoms of the dithiocine ligand and two Cl− ions. The dithiocine ligand forms a pair of metallacycle rings, with seven (C4S2Pd) and five (C2S2Pd) members, respectively. The benzylic part of the molecule is oriented away from the Pd atom, as a consequence of the boat conformation adopted by the chelating ligand. The geometry for both S-donor atoms is consistent with sp3 hybridization.http://scripts.iucr.org/cgi-bin/paper?S241431461600852Xcrystal structurepalladiumchelatedithiocinebidentate ligand |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Sylvain Bernès Jorge Tiburcio Hugo Torrens |
| spellingShingle |
Sylvain Bernès Jorge Tiburcio Hugo Torrens cis-Dichlorido(6,11-dihydrodibenzo[b,f][1,4]dithiocine-κ2S,S′)palladium(II) IUCrData crystal structure palladium chelate dithiocine bidentate ligand |
| author_facet |
Sylvain Bernès Jorge Tiburcio Hugo Torrens |
| author_sort |
Sylvain Bernès |
| title |
cis-Dichlorido(6,11-dihydrodibenzo[b,f][1,4]dithiocine-κ2S,S′)palladium(II) |
| title_short |
cis-Dichlorido(6,11-dihydrodibenzo[b,f][1,4]dithiocine-κ2S,S′)palladium(II) |
| title_full |
cis-Dichlorido(6,11-dihydrodibenzo[b,f][1,4]dithiocine-κ2S,S′)palladium(II) |
| title_fullStr |
cis-Dichlorido(6,11-dihydrodibenzo[b,f][1,4]dithiocine-κ2S,S′)palladium(II) |
| title_full_unstemmed |
cis-Dichlorido(6,11-dihydrodibenzo[b,f][1,4]dithiocine-κ2S,S′)palladium(II) |
| title_sort |
cis-dichlorido(6,11-dihydrodibenzo[b,f][1,4]dithiocine-κ2s,s′)palladium(ii) |
| publisher |
International Union of Crystallography |
| series |
IUCrData |
| issn |
2414-3146 |
| publishDate |
2016-06-01 |
| description |
In the title compound, [PdCl2(C14H12S2)], the PdII atom features a square-planar coordination to the two S atoms of the dithiocine ligand and two Cl− ions. The dithiocine ligand forms a pair of metallacycle rings, with seven (C4S2Pd) and five (C2S2Pd) members, respectively. The benzylic part of the molecule is oriented away from the Pd atom, as a consequence of the boat conformation adopted by the chelating ligand. The geometry for both S-donor atoms is consistent with sp3 hybridization. |
| topic |
crystal structure palladium chelate dithiocine bidentate ligand |
| url |
http://scripts.iucr.org/cgi-bin/paper?S241431461600852X |
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