cis-Dichlorido(6,11-dihydrodibenzo[b,f][1,4]dithiocine-κ2S,S′)palladium(II)

cis-Dichlorido(6,11-dihydrodibenzo[b,f][1,4]dithiocine-κ2S,S′)palladium(II)

In the title compound, [PdCl2(C14H12S2)], the PdII atom features a square-planar coordination to the two S atoms of the dithiocine ligand and two Cl− ions. The dithiocine ligand forms a pair of metallacycle rings, with seven (C4S2Pd) and five (C2S2Pd) members, respectively. The benzylic part of the...

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Bibliographic Details
Main Authors: Sylvain Bernès, Jorge Tiburcio, Hugo Torrens
Format: Article
Language:English
Published: International Union of Crystallography 2016-06-01
Series:IUCrData
Subjects:
crystal structure
palladium
chelate
dithiocine
bidentate ligand
Online Access:http://scripts.iucr.org/cgi-bin/paper?S241431461600852X
Description
Summary:In the title compound, [PdCl2(C14H12S2)], the PdII atom features a square-planar coordination to the two S atoms of the dithiocine ligand and two Cl− ions. The dithiocine ligand forms a pair of metallacycle rings, with seven (C4S2Pd) and five (C2S2Pd) members, respectively. The benzylic part of the molecule is oriented away from the Pd atom, as a consequence of the boat conformation adopted by the chelating ligand. The geometry for both S-donor atoms is consistent with sp3 hybridization.
ISSN:2414-3146

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