Stepwise Introduction of Different Substituents to α-Chloro-ω-hydrooligosilanes: Convenient Synthesis of Unsymmetrically Substituted Oligosilanes

Stepwise Introduction of Different Substituents to α-Chloro-ω-hydrooligosilanes: Convenient Synthesis of Unsymmetrically Substituted Oligosilanes

A series of unsymmetrically substituted oligosilanes were synthesized via stepwise introduction of different substituents to α-chloro-ω-hydrooligosilanes. The reactions of α-chloro-ω-hydrooligosilanes with organolithium or Grignard reagents gave hydrooligosila...

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Bibliographic Details
Main Authors: Ken-ichiro Kanno, Yumi Aikawa, Yuka Niwayama, Misaki Ino, Kento Kawamura, Soichiro Kyushin
Format: Article
Language:English
Published: MDPI AG 2018-09-01
Series:Inorganics
Subjects:
α-chloro-ω-hydrooligosilane
titanium
ruthenium
dehydrogenative alkoxylation
Online Access:http://www.mdpi.com/2304-6740/6/3/99

Internet

http://www.mdpi.com/2304-6740/6/3/99

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