Preparation of Poly(oxybutyleneoxymaleoyl) Catalyzed by a Proton Exchanged Montmorillonite Clay

The polycondensation of tetrahydrofuran with maleic anhydride catalyzed byMaghnite-H+ (Mag-H) was investigated. Maghnite is a montmorillonite sheet silicateclay that is exchanged with protons to produce Maghnite-H [1]. It was found that thepolymerization in bulk is initiated by Mag-H in the presence...

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Bibliographic Details
Main Authors: Mohammed Belbachir, Mohammed Issam Ferrahi
Format: Article
Language:English
Published: MDPI AG 2004-11-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/9/11/968/
Description
Summary:The polycondensation of tetrahydrofuran with maleic anhydride catalyzed byMaghnite-H+ (Mag-H) was investigated. Maghnite is a montmorillonite sheet silicateclay that is exchanged with protons to produce Maghnite-H [1]. It was found that thepolymerization in bulk is initiated by Mag-H in the presence of acetic anhydride at 40°C.The effects of the amounts of Mag-H and acetic anhydride were studied. Thepolymerization yield increased as the proportions of catalyst and acetic anhydride wereincreased.
ISSN:1420-3049