Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine

In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crys...

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Main Authors: Kannan Thirumurthy, Ganesamoorthy Thirunarayanan, S. Murugavel
Format: Article
Language:English
Published: International Union of Crystallography 2015-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015005794
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spelling doaj-1c5d990b94cf4a6baf3647bee5765efe2020-11-24T22:55:28ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-04-0171442142310.1107/S2056989015005794hb7384Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amineKannan Thirumurthy0Ganesamoorthy Thirunarayanan1S. Murugavel2Department of Chemistry, Annamalai University, Annamalainagar 608 002, Chidambaram, Tamilnadu, IndiaDepartment of Chemistry, Annamalai University, Annamalainagar 608 002, Chidambaram, Tamilnadu, IndiaDepartment of Physics, Thanthai Periyar Government Institute of Technology, Vellore 632 002, IndiaIn the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C—H...π and π—π interactions [centroid–centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S2056989015005794crystal structurecrystal packingquinolinecarbazole9-ethyl-9H-carbazol-3-amineC—H...π interactionsπ–π interactions
collection DOAJ
language English
format Article
sources DOAJ
author Kannan Thirumurthy
Ganesamoorthy Thirunarayanan
S. Murugavel
spellingShingle Kannan Thirumurthy
Ganesamoorthy Thirunarayanan
S. Murugavel
Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine
Acta Crystallographica Section E: Crystallographic Communications
crystal structure
crystal packing
quinoline
carbazole
9-ethyl-9H-carbazol-3-amine
C—H...π interactions
π–π interactions
author_facet Kannan Thirumurthy
Ganesamoorthy Thirunarayanan
S. Murugavel
author_sort Kannan Thirumurthy
title Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine
title_short Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine
title_full Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine
title_fullStr Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine
title_full_unstemmed Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine
title_sort crystal structure of (e)-n-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9h-carbazol-3-amine
publisher International Union of Crystallography
series Acta Crystallographica Section E: Crystallographic Communications
issn 2056-9890
publishDate 2015-04-01
description In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C—H...π and π—π interactions [centroid–centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supramolecular network.
topic crystal structure
crystal packing
quinoline
carbazole
9-ethyl-9H-carbazol-3-amine
C—H...π interactions
π–π interactions
url http://scripts.iucr.org/cgi-bin/paper?S2056989015005794
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