Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine
In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crys...
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International Union of Crystallography
2015-04-01
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doaj-1c5d990b94cf4a6baf3647bee5765efe2020-11-24T22:55:28ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902015-04-0171442142310.1107/S2056989015005794hb7384Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amineKannan Thirumurthy0Ganesamoorthy Thirunarayanan1S. Murugavel2Department of Chemistry, Annamalai University, Annamalainagar 608 002, Chidambaram, Tamilnadu, IndiaDepartment of Chemistry, Annamalai University, Annamalainagar 608 002, Chidambaram, Tamilnadu, IndiaDepartment of Physics, Thanthai Periyar Government Institute of Technology, Vellore 632 002, IndiaIn the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C—H...π and π—π interactions [centroid–centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S2056989015005794crystal structurecrystal packingquinolinecarbazole9-ethyl-9H-carbazol-3-amineC—H...π interactionsπ–π interactions |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Kannan Thirumurthy Ganesamoorthy Thirunarayanan S. Murugavel |
spellingShingle |
Kannan Thirumurthy Ganesamoorthy Thirunarayanan S. Murugavel Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine Acta Crystallographica Section E: Crystallographic Communications crystal structure crystal packing quinoline carbazole 9-ethyl-9H-carbazol-3-amine C—H...π interactions π–π interactions |
author_facet |
Kannan Thirumurthy Ganesamoorthy Thirunarayanan S. Murugavel |
author_sort |
Kannan Thirumurthy |
title |
Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine |
title_short |
Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine |
title_full |
Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine |
title_fullStr |
Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine |
title_full_unstemmed |
Crystal structure of (E)-N-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9H-carbazol-3-amine |
title_sort |
crystal structure of (e)-n-[(2-chloro-6-methoxyquinolin-3-yl)methylidene]-9-ethyl-9h-carbazol-3-amine |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2015-04-01 |
description |
In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C—H...π and π—π interactions [centroid–centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supramolecular network. |
topic |
crystal structure crystal packing quinoline carbazole 9-ethyl-9H-carbazol-3-amine C—H...π interactions π–π interactions |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989015005794 |
work_keys_str_mv |
AT kannanthirumurthy crystalstructureofen2chloro6methoxyquinolin3ylmethylidene9ethyl9hcarbazol3amine AT ganesamoorthythirunarayanan crystalstructureofen2chloro6methoxyquinolin3ylmethylidene9ethyl9hcarbazol3amine AT smurugavel crystalstructureofen2chloro6methoxyquinolin3ylmethylidene9ethyl9hcarbazol3amine |
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1725656064599261184 |