Poly[(μ3-5-tert-butylbenzene-1,3-dicarboxylato)dipyridinecobalt(II)]

Poly[(μ3-5-tert-butylbenzene-1,3-dicarboxylato)dipyridinecobalt(II)]

In the title compound, [Co(C12H12O4)(C5H5N)2]n, the CoII cation is coordinated by four O atoms from three 5-tert-butylbenzene-1,3-dicarboxylate anions and two N atoms from pyridine molecules in a distorted octahedral geometry. One carboxylate group of the anionic ligand chelates a CoII cation while...

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Main Authors: Kyungkyou Noh, Jaheon Kim
Format: Article
Language:English
Published: International Union of Crystallography 2013-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536813026640
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spelling doaj-1c54d593715d4bc38a1eefcb304dc8242020-11-25T00:12:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-11-016911m579m58010.1107/S1600536813026640Poly[(μ3-5-tert-butylbenzene-1,3-dicarboxylato)dipyridinecobalt(II)]Kyungkyou NohJaheon KimIn the title compound, [Co(C12H12O4)(C5H5N)2]n, the CoII cation is coordinated by four O atoms from three 5-tert-butylbenzene-1,3-dicarboxylate anions and two N atoms from pyridine molecules in a distorted octahedral geometry. One carboxylate group of the anionic ligand chelates a CoII cation while another carboxylate group bridges two CoII cations, resulting in a polymeric layer parallel to (101). Weak C—H...O hydrogen bonds occur between adjacent polymeric layers. In the crystal, one of pyridine molecules is equally disordered over two positions.http://scripts.iucr.org/cgi-bin/paper?S1600536813026640
collection DOAJ
language English
format Article
sources DOAJ
author Kyungkyou Noh
Jaheon Kim
spellingShingle Kyungkyou Noh
Jaheon Kim
Poly[(μ3-5-tert-butylbenzene-1,3-dicarboxylato)dipyridinecobalt(II)]
Acta Crystallographica Section E
author_facet Kyungkyou Noh
Jaheon Kim
author_sort Kyungkyou Noh
title Poly[(μ3-5-tert-butylbenzene-1,3-dicarboxylato)dipyridinecobalt(II)]
title_short Poly[(μ3-5-tert-butylbenzene-1,3-dicarboxylato)dipyridinecobalt(II)]
title_full Poly[(μ3-5-tert-butylbenzene-1,3-dicarboxylato)dipyridinecobalt(II)]
title_fullStr Poly[(μ3-5-tert-butylbenzene-1,3-dicarboxylato)dipyridinecobalt(II)]
title_full_unstemmed Poly[(μ3-5-tert-butylbenzene-1,3-dicarboxylato)dipyridinecobalt(II)]
title_sort poly[(μ3-5-tert-butylbenzene-1,3-dicarboxylato)dipyridinecobalt(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2013-11-01
description In the title compound, [Co(C12H12O4)(C5H5N)2]n, the CoII cation is coordinated by four O atoms from three 5-tert-butylbenzene-1,3-dicarboxylate anions and two N atoms from pyridine molecules in a distorted octahedral geometry. One carboxylate group of the anionic ligand chelates a CoII cation while another carboxylate group bridges two CoII cations, resulting in a polymeric layer parallel to (101). Weak C—H...O hydrogen bonds occur between adjacent polymeric layers. In the crystal, one of pyridine molecules is equally disordered over two positions.
url http://scripts.iucr.org/cgi-bin/paper?S1600536813026640
work_keys_str_mv AT kyungkyounoh poly95635tertbutylbenzene13dicarboxylatodipyridinecobaltii
AT jaheonkim poly95635tertbutylbenzene13dicarboxylatodipyridinecobaltii
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