{2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)

{2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)

In the title compound, [Cu(C17H30N2O2)(C3H7NO)2][SbF6]2, which is a potential catalyst in the asymmetric Gosteli–Claisen rearrangement, the Cu atom adopts a distorted cis-CuN2O2 square-planar geometry arising from N,N′-bidentate coordination by the chiral ligand and two O...

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Main Authors: Julia Rehbein, Markus Schürmann, Hans Preut, Martin Hiersemann
Format: Article
Language:English
Published: International Union of Crystallography 2009-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809020364
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spelling doaj-1c1ad2483133444ba710c98acb863b7d2020-11-25T00:53:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657m737m73710.1107/S1600536809020364{2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)Julia RehbeinMarkus SchürmannHans PreutMartin HiersemannIn the title compound, [Cu(C17H30N2O2)(C3H7NO)2][SbF6]2, which is a potential catalyst in the asymmetric Gosteli–Claisen rearrangement, the Cu atom adopts a distorted cis-CuN2O2 square-planar geometry arising from N,N′-bidentate coordination by the chiral ligand and two O-bonded dimethylformamide molecules. Two short C—H...O contacts occur within the ligand and two weak intermolecular C—H...F bonds may help to establish the packing. http://scripts.iucr.org/cgi-bin/paper?S1600536809020364
collection DOAJ
language English
format Article
sources DOAJ
author Julia Rehbein
Markus Schürmann
Hans Preut
Martin Hiersemann
spellingShingle Julia Rehbein
Markus Schürmann
Hans Preut
Martin Hiersemann
{2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)
Acta Crystallographica Section E
author_facet Julia Rehbein
Markus Schürmann
Hans Preut
Martin Hiersemann
author_sort Julia Rehbein
title {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)
title_short {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)
title_full {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)
title_fullStr {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)
title_full_unstemmed {2,2-Bis[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(N,N-dimethylformamide)copper(II) bis(hexafluoridoantimonate)
title_sort {2,2-bis[(4s)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]propane}bis(n,n-dimethylformamide)copper(ii) bis(hexafluoridoantimonate)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-07-01
description In the title compound, [Cu(C17H30N2O2)(C3H7NO)2][SbF6]2, which is a potential catalyst in the asymmetric Gosteli–Claisen rearrangement, the Cu atom adopts a distorted cis-CuN2O2 square-planar geometry arising from N,N′-bidentate coordination by the chiral ligand and two O-bonded dimethylformamide molecules. Two short C—H...O contacts occur within the ligand and two weak intermolecular C—H...F bonds may help to establish the packing.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809020364
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AT hanspreut 22bis4s4tertbutyl45dihydro13oxazol2ylpropanebisnndimethylformamidecopperiibishexafluoridoantimonate
AT martinhiersemann 22bis4s4tertbutyl45dihydro13oxazol2ylpropanebisnndimethylformamidecopperiibishexafluoridoantimonate
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