(2,4-Di-tert-butyl-6-{(E)-[(E)-2-(2-methoxybenzylideneamino)cyclohexyl]iminomethyl}phenolato)dimethylaluminum(III)

(2,4-Di-tert-butyl-6-{(E)-[(E)-2-(2-methoxybenzylideneamino)cyclohexyl]iminomethyl}phenolato)dimethylaluminum(III)

The title compound, [Al(CH3)2(C29H39N2O2)], exhibits disorder of one of the tert-butyl groups on the Schiff base ligand, where each methyl group is located over two sites, with occupancy factors of 0.57 (1) and 0.43 (1). The geometry around the AlIII atom is distorted tetrahedral...

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Main Author: Jin-Cai Wu
Format: Article
Language:English
Published: International Union of Crystallography 2009-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808041858
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spelling doaj-1bf63df16c9b48b38aa259c9544cec842020-11-24T22:08:24ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-01-01651m95m9510.1107/S1600536808041858(2,4-Di-tert-butyl-6-{(E)-[(E)-2-(2-methoxybenzylideneamino)cyclohexyl]iminomethyl}phenolato)dimethylaluminum(III)Jin-Cai WuThe title compound, [Al(CH3)2(C29H39N2O2)], exhibits disorder of one of the tert-butyl groups on the Schiff base ligand, where each methyl group is located over two sites, with occupancy factors of 0.57 (1) and 0.43 (1). The geometry around the AlIII atom is distorted tetrahedral, defined by two methyl groups, one N and one O atom from the Schiff base ligand.http://scripts.iucr.org/cgi-bin/paper?S1600536808041858
collection DOAJ
language English
format Article
sources DOAJ
author Jin-Cai Wu
spellingShingle Jin-Cai Wu
(2,4-Di-tert-butyl-6-{(E)-[(E)-2-(2-methoxybenzylideneamino)cyclohexyl]iminomethyl}phenolato)dimethylaluminum(III)
Acta Crystallographica Section E
author_facet Jin-Cai Wu
author_sort Jin-Cai Wu
title (2,4-Di-tert-butyl-6-{(E)-[(E)-2-(2-methoxybenzylideneamino)cyclohexyl]iminomethyl}phenolato)dimethylaluminum(III)
title_short (2,4-Di-tert-butyl-6-{(E)-[(E)-2-(2-methoxybenzylideneamino)cyclohexyl]iminomethyl}phenolato)dimethylaluminum(III)
title_full (2,4-Di-tert-butyl-6-{(E)-[(E)-2-(2-methoxybenzylideneamino)cyclohexyl]iminomethyl}phenolato)dimethylaluminum(III)
title_fullStr (2,4-Di-tert-butyl-6-{(E)-[(E)-2-(2-methoxybenzylideneamino)cyclohexyl]iminomethyl}phenolato)dimethylaluminum(III)
title_full_unstemmed (2,4-Di-tert-butyl-6-{(E)-[(E)-2-(2-methoxybenzylideneamino)cyclohexyl]iminomethyl}phenolato)dimethylaluminum(III)
title_sort (2,4-di-tert-butyl-6-{(e)-[(e)-2-(2-methoxybenzylideneamino)cyclohexyl]iminomethyl}phenolato)dimethylaluminum(iii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-01-01
description The title compound, [Al(CH3)2(C29H39N2O2)], exhibits disorder of one of the tert-butyl groups on the Schiff base ligand, where each methyl group is located over two sites, with occupancy factors of 0.57 (1) and 0.43 (1). The geometry around the AlIII atom is distorted tetrahedral, defined by two methyl groups, one N and one O atom from the Schiff base ligand.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808041858
work_keys_str_mv AT jincaiwu 24ditertbutyl6ee22methoxybenzylideneaminocyclohexyliminomethylphenolatodimethylaluminumiii
_version_ 1725816154783481856

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