Diacridinium tetrakis(thiocyanato-κS)platinate(II)

The asymmetric unit of the title compound, (C13H10N)2[Pt(NCS)4], contains a protonated acridine molecule and one half of a [Pt(NCS)4]2− anion. In the complex anion, the PtII ion is located on an inversion centre and is four-coordinated in a slightly distorted square-planar environment...

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Main Author: Kwang Ha
Format: Article
Language:English
Published: International Union of Crystallography 2010-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810002485
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spelling doaj-1bb407e28c6941dfa411365dc308b3762020-11-24T21:24:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m200m20010.1107/S1600536810002485Diacridinium tetrakis(thiocyanato-κS)platinate(II)Kwang HaThe asymmetric unit of the title compound, (C13H10N)2[Pt(NCS)4], contains a protonated acridine molecule and one half of a [Pt(NCS)4]2− anion. In the complex anion, the PtII ion is located on an inversion centre and is four-coordinated in a slightly distorted square-planar environment by four S atoms from four thiocyanate ligands. The compound displays numerous intermolecular π–π interactions between six-membered rings, with a shortest centroid–centroid distance of 3.682 (3) Å. The component ions interact by means of intermolecular N—H...N hydrogen bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536810002485
collection DOAJ
language English
format Article
sources DOAJ
author Kwang Ha
spellingShingle Kwang Ha
Diacridinium tetrakis(thiocyanato-κS)platinate(II)
Acta Crystallographica Section E
author_facet Kwang Ha
author_sort Kwang Ha
title Diacridinium tetrakis(thiocyanato-κS)platinate(II)
title_short Diacridinium tetrakis(thiocyanato-κS)platinate(II)
title_full Diacridinium tetrakis(thiocyanato-κS)platinate(II)
title_fullStr Diacridinium tetrakis(thiocyanato-κS)platinate(II)
title_full_unstemmed Diacridinium tetrakis(thiocyanato-κS)platinate(II)
title_sort diacridinium tetrakis(thiocyanato-κs)platinate(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-02-01
description The asymmetric unit of the title compound, (C13H10N)2[Pt(NCS)4], contains a protonated acridine molecule and one half of a [Pt(NCS)4]2− anion. In the complex anion, the PtII ion is located on an inversion centre and is four-coordinated in a slightly distorted square-planar environment by four S atoms from four thiocyanate ligands. The compound displays numerous intermolecular π–π interactions between six-membered rings, with a shortest centroid–centroid distance of 3.682 (3) Å. The component ions interact by means of intermolecular N—H...N hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810002485
work_keys_str_mv AT kwangha diacridiniumtetrakisthiocyanatoamp954splatinateii
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